Reversible thermo-sensitivity induced from varying the hydrogen bonding between the side residues of rationally designed polypeptides

作者: Hong Liu , Yan Xiao , Heng Xu , Yebin Guan , Jun Zhang

DOI: 10.1039/C5CC03017J

关键词: EthylenediamineHydrogen bondPolymer chemistryChemistryOrganic chemistrySensitivity (explosives)IsopropylamineSolubilityCopolymer

摘要: Rationally designed polypeptides with similar molecular structures but varying patterns of hydrogen bonding between the side groups have been synthesized and demonstrated to possess distinct solubility thermal behaviors. Further balancing ratio both isopropylamine ethylenediamine endows random copolymer reversible thermo-sensitivity.

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