Mathematical Models of the Homochiralisation of Crystals by Grinding
DOI: 10.1007/S11084-010-9221-2
关键词: Chirality (electromagnetism) 、 Mathematical model 、 Symmetry breaking 、 Crystal 、 Work (thermodynamics) 、 Grinding 、 Statistical physics 、 Physical chemistry 、 Chemistry 、 Space and Planetary Science 、 Ecology, Evolution, Behavior and Systematics 、 General Medicine
摘要: We review the existing mathematical models which describe physicochemical mechanisms capable of producing a symmetry-breaking transition to state in one chirality dominates other. A new model is proposed, with aim elucidating fundamental processes at work crystal grinding systems Viedma (Phys Rev Lett 94:065504, 2005) and Noorduin (J Am Chem Soc 130:1158–1159, 2008). simplify as far possible uncover competitive process causes symmetry-breaking, analyse other simplifications might be expected show symmetry-breaking.
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