Field dependence of hole mobility in TPD-doped polystyrene

作者: S. Raj Mohan , M.P. Joshi

DOI: 10.1016/J.SSC.2006.05.020

关键词: Field dependenceMicrostructureMolecular physicsDopingDopantMaterials scienceField (physics)Electron mobilityPolystyrenePhotoconductivityAnalytical chemistry

摘要: Abstract Field and temperature dependence of hole mobility in N , ′ -diphenyl- -bis(3-methylphenyl)-(1,1′-biphenyl)-4,4′-diamine (TPD) doped polystyrene (PS) is studied using the transient photoconductivity technique. We observe both positive negative field with increasing temperature. The at which begins low compared earlier reports on similar systems (with 20 wt% dopant concentration). Results are discussed basis Gaussian disorder model (GDM), predicts that interplay energetic positional molecules sample decides slope log μ versus E 1 / 2 plot. observed rationalized sample. reason for purely due to film morphology Even a concentration 20 wt%, we clustering chaining TPD molecules, may provide disorder.

参考文章(19)
Charles E Swenberg, Martin Pope, Electronic Processes in Organic Crystals and Polymers ,(1999)
Attila J. Mozer, Niyazi Serdar Sariciftci, Negative electric field dependence of charge carrier drift mobility in conjugated, semiconducting polymers Chemical Physics Letters. ,vol. 389, pp. 438- 442 ,(2004) , 10.1016/J.CPLETT.2004.04.001
P.M. Borsenberger, W.T. Gruenbaum, E.H. Magin, Hole transport in bis(ditolylaminostyryl)benzene doped poly(styrene) Physica B-condensed Matter. ,vol. 228, pp. 233- 238 ,(1996) , 10.1016/0921-4526(96)88799-0
Hiroshi Kageyama, Katsuhei Ohnishi, Satoyuki Nomura, Yasuhiko Shirota, Negative electric-field dependence of hole drift mobility for a molecular glass of tri(o-terphenyl-4-yl)amine Chemical Physics Letters. ,vol. 277, pp. 137- 141 ,(1997) , 10.1016/S0009-2614(97)00872-5
P. M. Borsenberger, L. Pautmeier, H. Bässler, Charge transport in disordered molecular solids The Journal of Chemical Physics. ,vol. 94, pp. 5447- 5454 ,(1991) , 10.1063/1.460506
Marı́a A. Dı́az-Garcı́a, Susana Fernández De Ávila, Mark G. Kuzyk, Dye-doped polymers for blue organic diode lasers Applied Physics Letters. ,vol. 80, pp. 4486- 4488 ,(2002) , 10.1063/1.1485303
Anto Regis Inigo, Hsiang-Chih Chiu, Wunshain Fann, Ying-Sheng Huang, U-Ser Jeng, Tsang-Lang Lin, Chia-Hung Hsu, Kang-Yung Peng, Show-An Chen, Disorder controlled hole transport in MEH-PPV Physical Review B. ,vol. 69, pp. 075201- ,(2004) , 10.1103/PHYSREVB.69.075201
B. Hartenstein, H. Bässler, S. Heun, P. Borsenberger, M. Van der Auweraer, F.C. De Schryver, Charge transport in molecularly doped polymers at low dopant concentrations: simulation and experiment Chemical Physics. ,vol. 191, pp. 321- 332 ,(1995) , 10.1016/0301-0104(94)00329-9
S. Heun, P.M. Borsenberger, Hole transport in triarylamine doped polymers Physica B-condensed Matter. ,vol. 216, pp. 43- 52 ,(1995) , 10.1016/0921-4526(95)00444-0