Determining the geographical origin of Sechium edule fruits by multielement analysis and advanced chemometric techniques.
作者： Melisa J. Hidalgo , Diana C. Fechner , Eduardo J. Marchevsky , Roberto G. Pellerano
DOI: 10.1016/J.FOODCHEM.2016.04.120
关键词: Inductively coupled plasma 、 Inductively coupled plasma atomic emission spectroscopy 、 Principal component analysis 、 Chemistry 、 Microwave digestion 、 Sechium 、 Analytical chemistry 、 Trace element composition 、 Optical emission spectrometry 、 Linear discriminant analysis
摘要: This paper describes the determination and evaluation of major trace element composition (Al, As, Ba, Ca, Cd, Co, Cu, Fe, K, Mg, Mn, Na, Pb, Sr Zn) Sechium edule (Jacq) Swartz fruits collected from four different places production in Corrientes province, Argentina. Element concentrations were determined by using inductively coupled plasma optical emission spectrometry (ICP OES) after microwave digestion. The accuracy was confirmed with standard reference material spinach leaves (NIST, 1570a) spiking tests. Principal component analysis (PCA), linear discriminant (LDA), k-nearest neighbors (kNN), partial least square-discriminant (PLS-DA) support vector machine (SVM) applied to results for discriminating geographical origin S. fruits. Finally, LDA method found perform best up 90% rate based on following elements: Sr, Zn.
sci-hub.se 参考文章(28)
B.K. Lavine, W.S. Rayens, Statistical Discriminant Analysis Reference Module in Chemistry, Molecular Sciences and Chemical Engineering#R##N#Comprehensive Chemometrics#R##N#Chemical and Biochemical Data Analysis. ,vol. 3, pp. 517- 540 ,(2009) , 10.1016/B978-044452701-1.00024-7
Marta Bevilacqua, Remo Bucci, Andrea D. Magrì, Antonio L. Magrì, Riccardo Nescatelli, Federico Marini, Classification and Class-Modelling Data Handling in Science and Technology. ,vol. 28, pp. 171- 233 ,(2013) , 10.1016/B978-0-444-59528-7.00005-3
Mario Li Vigni, Caterina Durante, Marina Cocchi, Exploratory Data Analysis Data Handling in Science and Technology. ,vol. 28, pp. 55- 126 ,(2013) , 10.1016/B978-0-444-59528-7.00003-X
L J Guppy, M Nelson, E A Gordon, The antihypertensive effects of the Jamaican Cho-Cho (Sechium edule). West Indian Medical Journal. ,vol. 49, pp. 27- 31 ,(2000)
Louis H. Aung, Amelia Ball, Mosbah Kushad, Developmental and nutritional aspects of chayote (Sechium edule, Cucurbitaceae) Economic Botany. ,vol. 44, pp. 157- 164 ,(1990) , 10.1007/BF02860483
Richard G. Brereton, Gavin R. Lloyd, Partial least squares discriminant analysis: taking the magic away Journal of Chemometrics. ,vol. 28, pp. 213- 225 ,(2014) , 10.1002/CEM.2609
陳佩君, Support Vector Machines ,(2008)
Max Kuhn, Building Predictive Models in R Using the caret Package Journal of Statistical Software. ,vol. 28, pp. 1- 26 ,(2008) , 10.18637/JSS.V028.I05
Davide Ballabio, Viviana Consonni, Classification tools in chemistry. Part 1: linear models. PLS-DA Analytical Methods. ,vol. 5, pp. 3790- 3798 ,(2013) , 10.1039/C3AY40582F
Pascal Leterme, André Buldgen, Fernando Estrada, Angela M. Londoño, Mineral content of tropical fruits and unconventional foods of the Andes and the rain forest of Colombia Food Chemistry. ,vol. 95, pp. 644- 652 ,(2006) , 10.1016/J.FOODCHEM.2005.02.003