Epoxidation of hydroxyl-terminated polybutadiene with hydrogen peroxide under phase-transfer catalysis
作者： Qingfa Wang , Xiangwen Zhang , Li Wang , Zhentao Mi
DOI: 10.1016/J.MOLCATA.2009.04.019
关键词: Hydroxyl-terminated polybutadiene 、 Aliquat 336 、 Inorganic chemistry 、 Hydrogen peroxide 、 Tungstate 、 Catalysis 、 Chemistry 、 Ammonium 、 Hydrate 、 Phosphoric acid
摘要: Abstract The phase-transfer catalytic epoxidation of hydroxyl-terminated polybutadiene (HTPB) by hydrogen peroxide was investigated using quaternary ammonium salts, tungstate hydrate and phosphoric acid as the catalyst cocatalysts, respectively. influences amount Aliquat 336 peroxide, molar ratio to (PO 4 3− /WO 2− ), pH value organic solvents on conversion double bonds in HTPB polymer were studied detail. kinetic also discussed apparent activated energy for estimated be 21.04 kJ/mol.
elsevier.com
sci-hub.se 参考文章(44)
George Wypych, Handbook of Solvents ,(2000)
J. P. Arlie, Synthetic Rubbers: Processes and Economic Data ,(1992)
Christian Reichardt, Solvents and Solvent Effects in Organic Chemistry ,(1988)
Allan F. M. Barton, CRC Handbook of Solubility Parameters and Other Cohesion Parameters Barton, A.F.M. <https://researchrepository.murdoch.edu.au/view/author/Barton, Allan.html> (2017) CRC Handbook of Solubility Parameters and Other Cohesion Parameters. Routledge as part of the Taylor and Francis group, New York.. ,(1983)
Marcelo Aguiar, Sonia Cabral de Menezes, Leni Akcelrud, Configurational double bond selectivity in the epoxidation of hydroxy-terminated polybutadiene with m-chloroperbenzoic acid Macromolecular Chemistry and Physics. ,vol. 195, pp. 3937- 3948 ,(1994) , 10.1002/MACP.1994.021951219
Yasuhiko Kurusu, Functionalization of polymers: Epoxidation of polyolefins Polymers for Advanced Technologies. ,vol. 7, pp. 67- 72 ,(1996) , 10.1002/(SICI)1099-1581(199602)7:2<67::AID-PAT452>3.0.CO;2-W
Leigh Clawson, Stephen L. Buchwald, Robert H. Grubbs, The methylenation of enolizable ketones and esters using organotitanium chemistry Tetrahedron Letters. ,vol. 25, pp. 5733- 5736 ,(1984) , 10.1016/S0040-4039(01)81672-5
Maw-Ling Wang, Tsuan-Hsuan Huang, Wen-Teng Wu, KINETIC STUDY OF THE PHASE TRANSFER CATALYTIC EPOXIDATION OF DICYCLOPENTADIENE IN A TWO-PHASE MEDIUM Chemical Engineering Communications. ,vol. 191, pp. 27- 46 ,(2004) , 10.1081/00986440490262826
Shih-Liang Huang, Juin-Yih Lai, On the gas permeability of hydroxyl terminated polybutadiene based polyurethane membranes Journal of Membrane Science. ,vol. 105, pp. 137- 145 ,(1995) , 10.1016/0376-7388(94)00319-T
Xuehui Wang, Huixuan Zhang, Zhigang Wang, Bingzheng Jiang, In situ epoxidation of ethylene propylene diene rubber by performic acid Polymer. ,vol. 38, pp. 5407- 5410 ,(1997) , 10.1016/S0032-3861(97)00043-8