Spreading of surfactant solutions over thin aqueous layers at low concentrations: Influence of solubility.

作者: K.S. Lee , V.M. Starov

DOI: 10.1016/J.JCIS.2008.10.031

关键词: Analytical chemistryFront (oceanography)RadiusTime evolutionPulmonary surfactantChemistryVolume concentrationMineralogyAqueous solutionSolubilityMarangoni effect

摘要: A small droplet of aqueous surfactant solution at concentration below CMC was deposited on a thin water layer. moving circular wave in the centre formed. The time evolution radius monitored. Two surfactants different solubility were used. It shown that front (i) proceeds two stages: fast first stage and slower second stage; (ii) motion substantially depends solubility. We suggest qualitative explanation phenomenon, which reasonably agrees with our experimental observations.

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