Comparison of ZrO2:Y nanocrystals and macroscopic single crystal luminescence
作者： K Smits , D Millers , L Grigorjeva , J D Fidelus , W Lojkowski
DOI: 10.1088/1742-6596/93/1/012035
关键词: Single crystal 、 Spectral line 、 Excitation 、 Band gap 、 Nanocrystal 、 Charge carrier 、 Zirconium 、 Crystallography 、 Luminescence 、 Materials science
摘要: The luminescence spectra of a tetragonally structured ZrO2:Y single crystal and nanocrystals were compared. It was found that the number centers contributed to spectra. excitation within band gap region led different for nanocrystal samples, whereas recombinative same both samples. origin this difference is in nanocrystals, even under gap, charge carriers created. Zirconium- oxygen complexes distorted by intrinsic defects proposed be centres responsible wide observed.
sci-hub.se 参考文章(12)
Marco Kirm, Jaan Aarik, Meelis Jürgens, Ilmo Sildos, Thin films of HfO2 and ZrO2 as potential scintillators Nuclear Instruments & Methods in Physics Research Section A-accelerators Spectrometers Detectors and Associated Equipment. ,vol. 537, pp. 251- 255 ,(2005) , 10.1016/J.NIMA.2004.08.020
N. G. Petrik, D. P. Taylor, T. M. Orlando, Laser-stimulated luminescence of yttria-stabilized cubic zirconia crystals Journal of Applied Physics. ,vol. 85, pp. 6770- 6776 ,(1999) , 10.1063/1.370192
Jiahe Liang, Xin Jiang, Ge Liu, Zhaoxiang Deng, Jing Zhuang, Fuli Li, Yadong Li, Characterization and synthesis of pure ZrO2 nanopowders via sonochemical method Materials Research Bulletin. ,vol. 38, pp. 161- 168 ,(2003) , 10.1016/S0025-5408(02)01007-3
C. B. Azzoni, A. Paleari, Photoactivation of hole-centers in cubic stabilized zirconia Physical Review B. ,vol. 53, pp. 5- 8 ,(1996) , 10.1103/PHYSREVB.53.5
Francesco Vissani, Do experiments suggest a hierarchy problem? Physical Review D. ,vol. 57, pp. 7027- 7030 ,(1998) , 10.1103/PHYSREVD.57.7027
G. Stapper, M. Bernasconi, N. Nicoloso, M. Parrinello, Ab initio study of structural and electronic properties of yttria-stabilized cubic zirconia Physical Review B. ,vol. 59, pp. 797- 810 ,(1999) , 10.1103/PHYSREVB.59.797
Balázs Králik, Eric K. Chang, Steven G. Louie, Structural properties and quasiparticle band structure of zirconia Physical Review B. ,vol. 57, pp. 7027- 7036 ,(1998) , 10.1103/PHYSREVB.57.7027
Junko Kondo, Kazunari Domen, Ken-Ichi Maruya, Takaharu Onishi, Masakazu Anpo, Takaiki Nomura, Photoluminescence and FT-IR studies of the dissociative adsorption of H2 on the active ZrO2 catalyst and its role in the hydrogenation of CO Research on Chemical Intermediates. ,vol. 13, pp. 195- 202 ,(1990) , 10.1163/156856790X00085
Lee-Jene Lai, Ching-Shen Su, Luminescence excitation and near edge X-ray absorption spectra of Er2O3 dopant on zirconia ceramics Materials Chemistry and Physics. ,vol. 62, pp. 148- 152 ,(2000) , 10.1016/S0254-0584(99)00172-8
S E Paje, J Llopis, Disorder effects on the luminescence decay in yttria-stabilized zirconia polycrystals Journal of Physics D. ,vol. 29, pp. 442- 445 ,(1996) , 10.1088/0022-3727/29/2/023