Highly visible-light active nanoporous TiO2 photocatalysts for efficient solar photocatalytic applications
作者： Hyun Uk Lee , Soon Chang Lee , Sae Hae Choi , Byoungchul Son , Soo Jae Lee
DOI: 10.1016/J.APCATB.2012.09.010
关键词: Photocatalysis 、 Thermal treatment 、 Sol-gel 、 Nanoporous 、 Titanium dioxide 、 Visible spectrum 、 Anatase 、 Nuclear chemistry 、 Nanotechnology 、 Crystallite 、 Materials science
摘要: We report highly visible-light active nanoporous carbon-doped TiO2 (C-TiO2) and sulfur-doped TiO2 (S-TiO2) for environmental and biomedical applications. C-TiO2 and S-TiO2 were synthesized at room temperature without thermal treatment using modified sol–gel processing and ultrasound irradiation. Under visible-light irradiation, the highest photocatalytic activity for S-TiO2 ([k]= 3.121 h− 1) was found to be 28 times higher than that of undoped nanoporous TiO2 ([k]= 0.112 h− 1). The recyclability of the S-TiO2 photocatalyst …
sci-hub.se 参考文章(69)
Daimei Chen, Zhongyi Jiang, Jiaqing Geng, Qun Wang, Dong Yang, Carbon and Nitrogen Co-doped TiO2 with Enhanced Visible-Light Photocatalytic Activity Industrial & Engineering Chemistry Research. ,vol. 46, pp. 2741- 2746 ,(2007) , 10.1021/IE061491K
Qi Xiao, Linli Ouyang, Photocatalytic activity and hydroxyl radical formation of carbon-doped TiO2 nanocrystalline: Effect of calcination temperature Chemical Engineering Journal. ,vol. 148, pp. 248- 253 ,(2009) , 10.1016/J.CEJ.2008.08.024
X YANG, C CAO, K HOHN, L ERICKSON, R MAGHIRANG, D HAMAL, K KLABUNDE, Highly visible-light active C- and V-doped TiO2 for degradation of acetaldehyde Journal of Catalysis. ,vol. 252, pp. 296- 302 ,(2007) , 10.1016/J.JCAT.2007.09.014
Jimmy C. Yu, Yu, Ho, Jiang, Zhang, Effects of F- Doping on the Photocatalytic Activity and Microstructures of Nanocrystalline TiO2 Powders Chemistry of Materials. ,vol. 14, pp. 3808- 3816 ,(2002) , 10.1021/CM020027C
Hua Tong, Shuxin Ouyang, Yingpu Bi, Naoto Umezawa, Mitsutake Oshikiri, Jinhua Ye, Nano‐photocatalytic Materials: Possibilities and Challenges Advanced Materials. ,vol. 24, pp. 229- 251 ,(2012) , 10.1002/ADMA.201102752
Saurabh S. Soni, Mark J. Henderson, Jean-François Bardeau, Alain Gibaud, Visible‐Light Photocatalysis in Titania‐Based Mesoporous Thin Films Advanced Materials. ,vol. 20, pp. 1493- 1498 ,(2008) , 10.1002/ADMA.200701066
Dong Suk Kim, Seung-Yeop Kwak, The hydrothermal synthesis of mesoporous TiO2 with high crystallinity, thermal stability, large surface area, and enhanced photocatalytic activity Applied Catalysis A-general. ,vol. 323, pp. 110- 118 ,(2007) , 10.1016/J.APCATA.2007.02.010
Yoon-Chae Nah, Indhumati Paramasivam, Patrik Schmuki, Doped TiO2 and TiO2 Nanotubes: Synthesis and Applications ChemPhysChem. ,vol. 11, pp. 2698- 2713 ,(2010) , 10.1002/CPHC.201000276
Isao Nakamura, Nobuaki Negishi, Shuzo Kutsuna, Tatsuhiko Ihara, Shinichi Sugihara, Koji Takeuchi, Role of oxygen vacancy in the plasma-treated TiO2 photocatalyst with visible light activity for NO removal Journal of Molecular Catalysis A-chemical. ,vol. 161, pp. 205- 212 ,(2000) , 10.1016/S1381-1169(00)00362-9
Christophe Cantau, Thierry Pigot, Jean-Charles Dupin, Sylvie Lacombe, None, N-doped TiO2 by low temperature synthesis: Stability, photo-reactivity and singlet oxygen formation in the visible range Journal of Photochemistry and Photobiology A-chemistry. ,vol. 216, pp. 201- 208 ,(2010) , 10.1016/J.JPHOTOCHEM.2010.08.004