Complex electrical transport behavior in low temperature sintered M-type hexaferrites

作者: Long Peng , Lezhong Li , Xiaoqiang Tu , Rui Wang , Yun Hu

DOI: 10.1016/J.JMMM.2015.10.068

关键词: Electrical resistivity and conductivityThermalThermal conductionAnalytical chemistryMaterials scienceCondensed matter physicsType (model theory)Phase (matter)OctahedronExcitationElectron

摘要: Abstract Temperature dependence of resistivity from room temperature to 750 °C at different frequency for the low sintered Sr 1− x La Fe 12− Co O 19 ( =0–0.3) ferrites was investigated, and a theory model based on hybrid grain structure established explain observed complex electrical transport behavior. It indicates that formation surface phase associated with non-uniform 3+ –Co 2+ substitution is crucial structure, which consists body phase, interface. The abnormal double metal-semiconductor (M–S) transitions in substituted are suggested arise competition lattice vibration scattering effect thermal excitation conduction electrons strongly correlated hopping between octahedral sites phase.

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