Untersuchungen zur optischen rotations-dispersion und zum circulardichroismus—XI : Quadrantenregel für den n → π*-Cotton-effekt von dithiocarbamaten und dithiourethanen chiraler amine☆
作者： H. Ripperger
DOI: 10.1016/0040-4020(69)85004-0
关键词: Octant (solid geometry) 、 Crystallography 、 Quadrant (plane geometry) 、 Polymer chemistry 、 Chemistry 、 Sign (mathematics)
摘要: Abstract Several asymmetric dithiocarbamates and dithiourethanes were synthesized their n → π* Cotton effects measured. A simple quadrant rule is given predicting the sign of these effects. This useful in solving stereochemical problems a manner analogous to octant for ketones.
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