High-Pressure Synthesis ofγ-P3N5 at 11 GPa and 1500 °C in a Multianvil Assembly: A Binary Phosphorus(V) Nitride with a Three-Dimensional Network Structure from PN4 Tetrahedra and Tetragonal PN5 Pyramids
作者： Kai Landskron , Hubert Huppertz , Jürgen Senker , Wolfgang Schnick
DOI: 10.1002/1521-3773(20010716)40:14<2643::AID-ANIE2643>3.0.CO;2-T
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摘要: Extreme reaction conditions lead to the synthesis of γ-P3 N5 . Its crystal structure, unlike that normal pressure modification α-P3 , is not exclusively built from PN4 tetrahedra, but both tetrahedra (blue) and tetragonal PN5 pyramids (red). A pyramid structure element has been observed previously.
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