The metal–carbon–fluorine system for improving hydrogen storage by using metal and fluorine with different levels of electronegativity

作者: J IM , S PARK , Y LEE

DOI: 10.1016/J.IJHYDENE.2008.11.054

关键词:

摘要: Abstract In order to improve the capacity of hydrogen storage using activated carbon nanofibers, metal and fluorine were introduced into nanofibers by electrospinning, heat treatment, direct fluorination. The pore structure samples was developed KOH activation process investigated nitrogen isotherms micropore size distribution. specific surface area total volume approached 2800 m2/g 2.7 cc/g, respectively. Because electronegativity gap between two elements (metal fluorine), electron a molecule can be attracted one side. This reaction effectively guides nanofibers. amount dramatically increased in this metal–carbon–fluorine system; content as high 3.2 wt%.

参考文章(21)
Y. Liu, C.M. Brown, J.L. Blackburn, D.A. Neumann, T. Gennett, L. Simpson, P. Parilla, A.C. Dillon, M.J. Heben, Inelastic neutron scattering of H2 adsorbed on boron substituted single walled carbon nanotubes Journal of Alloys and Compounds. ,vol. 446, pp. 368- 372 ,(2007) , 10.1016/J.JALLCOM.2007.01.113
Ji Sun Im, Soo-Jin Park, Tae Jin Kim, Young Ho Kim, Young-Seak Lee, The study of controlling pore size on electrospun carbon nanofibers for hydrogen adsorption Journal of Colloid and Interface Science. ,vol. 318, pp. 42- 49 ,(2008) , 10.1016/J.JCIS.2007.10.024
A. M. Seayad, D. M. Antonelli, RECENT ADVANCES IN HYDROGEN STORAGE IN METAL-CONTAINING INORGANIC NANOSTRUCTURES AND RELATED MATERIALS Advanced Materials. ,vol. 16, pp. 765- 777 ,(2004) , 10.1002/ADMA.200306557
Ji Sun Im, Soo-Jin Park, Young-Seak Lee, Preparation and characteristics of electrospun activated carbon materials having meso- and macropores Journal of Colloid and Interface Science. ,vol. 314, pp. 32- 37 ,(2007) , 10.1016/J.JCIS.2007.05.033
Fatma O. Erdogan, Turkan Kopac, Dynamic analysis of sorption of hydrogen in activated carbon International Journal of Hydrogen Energy. ,vol. 32, pp. 3448- 3456 ,(2007) , 10.1016/J.IJHYDENE.2007.02.009
An-Hui Lu, Jing-Tang Zheng, Microstructures of PAN-ACF modified by catalytic benzene deposition Carbon. ,vol. 40, pp. 1353- 1361 ,(2002) , 10.1016/S0008-6223(01)00293-7
Ji Sun Im, Ohseob Kwon, Young Ho Kim, Soo-Jin Park, Young-Seak Lee, The effect of embedded vanadium catalyst on activated electrospun CFs for hydrogen storage Microporous and Mesoporous Materials. ,vol. 115, pp. 514- 521 ,(2008) , 10.1016/J.MICROMESO.2008.02.027
A.C. Dillon, M.J. Heben, Hydrogen storage using carbon adsorbents: past, present and future Applied Physics A. ,vol. 72, pp. 133- 142 ,(2001) , 10.1007/S003390100788
Gene D. Berry, Salvador M. Aceves, Onboard Storage Alternatives for Hydrogen Vehicles Energy & Fuels. ,vol. 12, pp. 49- 55 ,(1998) , 10.1021/EF9700947
Nor Hasridah Abu Hassan, Abdul Rahman Mohamed, Sharif Hussein Sharif Zein, Study of hydrogen storage by carbonaceous material at room temperature Diamond and Related Materials. ,vol. 16, pp. 1517- 1523 ,(2007) , 10.1016/J.DIAMOND.2006.12.042