Study on Microstructure and Properties of BTBY Piezoelectric Ceramics with High Curie Temperature

作者: Bo Li , Feng Gao , Liang Liang Liu , Bei Xu

DOI: 10.4028/WWW.SCIENTIFIC.NET/AMR.156-157.1541

关键词:

摘要: (1-x)(0.6BIT-0.4BT)-xBiYbO3(BTBY) ceramics with high Curie temperature were prepared by the conventional processing. The effect of BiYbO3 content on the microstructure and electrical properties was investigated. The results show that the main phase of BTBY ceramics is BIT-BT, and a new phase BaBi4Ti4O15 (BBT) appeared. The grain morphology of BTPY ceramics are platelike and the grain size was significantly increased with increasing content of BiYbO3 .Tc of all the BTBY samples are above 440 . The BTBY ceramics show obvious dielectric relaxor characteristic. The dispersion factor γ, the dielectric constant εr, and the dielectric loss tanδ decreased with increasing the content of BiYbO3. When the content of BiYbO3 is 0.06, the optimal properties of BTBY ceramics are obtained, Tc is 457 , εr is 165, tanδ is 0.0223 and d33 is 10 pC·N-1.

参考文章(7)
Richard E. Eitel, Clive A. Randall, Thomas R. Shrout, Paul W. Rehrig, Wes Hackenberger, Seung-Eek Park, New High Temperature Morphotropic Phase Boundary Piezoelectrics Based on Bi(Me)O3?PbTiO3 Ceramics Japanese Journal of Applied Physics. ,vol. 40, pp. 5999- 6002 ,(2001) , 10.1143/JJAP.40.5999
Tadashi Takenaka, Hajime Nagata, Current status and prospects of lead-free piezoelectric ceramics Journal of The European Ceramic Society. ,vol. 25, pp. 2693- 2700 ,(2005) , 10.1016/J.JEURCERAMSOC.2005.03.125
Gao Feng, Hong Rongzi, Liu Jiaji, Li Zhen, Cheng Lihong, Tian Changsheng, Phase formation and characterization of high Curie temperature xBiYbO3–(1 − x)PbTiO3 piezoelectric ceramics Journal of The European Ceramic Society. ,vol. 29, pp. 1687- 1693 ,(2009) , 10.1016/J.JEURCERAMSOC.2008.09.024
Seema Sharma, D.A. Hall, Preeti S. Mulage, Structural studies of BiFeO3 modified BMZ-PT ceramics Materials Letters. ,vol. 61, pp. 3352- 3356 ,(2007) , 10.1016/J.MATLET.2006.11.096
Si Chen, Xianlin Dong, Chaoliang Mao, Fei Cao, Thermal Stability of (1−x)BiScO3−xPbTiO3 Piezoelectric Ceramics for High-Temperature Sensor Applications Journal of the American Ceramic Society. ,vol. 89, pp. 3270- 3272 ,(2006) , 10.1111/J.1551-2916.2006.01201.X
N. Setter, L. E. Cross, The Role of B-Site Cation Disorder in Diffuse Phase-Transition Behavior of Perovskite Ferroelectrics Journal of Applied Physics. ,vol. 51, pp. 4356- 4360 ,(1980) , 10.1063/1.328296
M.D. Snel, W.A. Groen, G. de With, New Bi(Mg0.75W0.25)O3-PbTiO3 ferroelectric ceramics Journal of The European Ceramic Society. ,vol. 26, pp. 89- 93 ,(2006) , 10.1016/J.JEURCERAMSOC.2004.10.022