Synthesis, Structure, and Properties of a T-Shaped 14-Electron Stiboranyl-Gold Complex
作者： Casey R. Wade , Tzu-Pin Lin , Ryan C. Nelson , Elizabeth A. Mader , Jeffrey T. Miller
DOI: 10.1021/JA201092G
关键词:
摘要: A cyclic stiboranyl-gold complex (1) supported by two 1,8-naphthalenediyl linkers has been synthesized and structurally characterized. The gold atom of this adopts a T-shaped geometry is separated from the antimony center only 2.76 A. Surprisingly, trivalent involved in an aurophilic interaction, phenomenon typically observed for monovalent complexes. This indicates that stiboranyl ligand possesses strong σ-donating properties making 1 electron rich. view DFT calculations as well Au L3- Sb K-edge XANES spectra which reveal may also be described aurate-stibonium derivative. In agreement with view, shows no reactivity toward halides Cl–, Br–, I–. It does, however, rapidly react F– to form unprecedented anionic aurate fluorostiborane ([2]−) isolated tetra-n-butylammonium salt. increased coordination numb...
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Rafael Uson, Antonio Laguna, Mariano Laguna, D. A. Briggs, H. H. Murray, J. P. Fackler, (Tetrahydrothiophene)Gold(I) or Gold(III) Complexes Inorganic Syntheses. pp. 85- 91 ,(2007) , 10.1002/9780470132579.CH17
Mitsutoshi Kimura, Akiyuki Iwata, Masahiro Itoh, Kazuki Yamada, Tsutomu Kimura, Noriyuki Sugiura, Masaru Ishida, Shinzi Kato, Synthesis, Structures, and Some Reactions of [(Thioacyl)thio]‐ and (Acylseleno)antimony and ‐bismuth Derivatives ((RCSS)xMR$\rm{_{{\bf 3 - }{\bf x}}^{\bf 1} }$ and (RCOSe)xMR$\rm{_{{\bf 3 - }{\bf x}}^{\bf 1} }$ with M = Sb, Bi and x = 1–3) Helvetica Chimica Acta. ,vol. 89, pp. 747- 783 ,(2006) , 10.1002/HLCA.200690070
Wolfgang Malisch, Peter Panster, Antimony(V)‐Transition Metal Compounds with Covalent and Ionic Character Angewandte Chemie. ,vol. 13, pp. 670- 672 ,(1974) , 10.1002/ANIE.197406702
William Levason, Gillian Reid, Developments in the coordination chemistry of stibine ligands Coordination Chemistry Reviews. ,vol. 250, pp. 2565- 2594 ,(2006) , 10.1016/J.CCR.2006.03.024
Matthew T. Whited, Neal P. Mankad, Yunho Lee, Paul F. Oblad, Jonas C. Peters, Dinitrogen Complexes Supported by Tris(phosphino)silyl Ligands Inorganic Chemistry. ,vol. 48, pp. 2507- 2517 ,(2009) , 10.1021/IC801855Y
Wolfgang Neugebauer, Timothy Clark, Paul von Ragué Schleyer, Regioselektive Metallierung von Aromaten, II. Zweitmetallierung von 1-Lithionaphthalin und 9-Lithioanthracen Chemische Berichte. ,vol. 116, pp. 3283- 3292 ,(1983) , 10.1002/CBER.19831161003
Abderrahmane Amgoune, Didier Bourissou, σ-Acceptor, Z-type ligands for transition metals Chemical Communications. ,vol. 47, pp. 859- 871 ,(2011) , 10.1039/C0CC04109B
Koichiro Toyota, Yukiya Wakisaka, Yohsuke Yamamoto, Kin-ya Akiba, Evidence for Intramolecular Permutation (Pseudorotation) at the Central Antimony Atom and Strong Equatophilicity of an Iron and a Ruthenium Ligand in Pentacoordinate Hypervalent Antimony Compounds Organometallics. ,vol. 19, pp. 5122- 5133 ,(2000) , 10.1021/OM000790L
S. E. Fawcett, R. A. Gordon, H. E. Jamieson, Optimizing experimental design, overcoming challenges, and gaining valuable information from the Sb K-edge XANES region American Mineralogist. ,vol. 94, pp. 1377- 1387 ,(2009) , 10.2138/AM.2009.3112
Yasutomo Segawa, Makoto Yamashita, Kyoko Nozaki, Syntheses of PBP Pincer Iridium Complexes: A Supporting Boryl Ligand Journal of the American Chemical Society. ,vol. 131, pp. 9201- 9203 ,(2009) , 10.1021/JA9037092