Synthesis of oligoarylamines, and uses and reagents related thereto
作者： Joseph P. Sadighi , Stephen L. Buchwald , Thomas Mackewitz , Robert A. Singer
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摘要: The transition metal-catalysed amination of aryl halides, in conjunction with an orthogonal protective group scheme, forms the basis two routes to oligoaniline precursors. precursors are soluble a variety common organic solvents, and easily converted deprotected oligoanilines. method allows preparation oligoanilines even or odd chain lengths, incorporation functional groups into oligomers. Polyanilines low polydispersity can also be prepared by this method.
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