Electrochemiluminescent swimmers for dynamic enzymatic sensing.

作者: Milica Sentic , Stéphane Arbault , Bertrand Goudeau , Dragan Manojlovic , Alexander Kuhn

DOI: 10.1039/C4CC04105D

关键词:

摘要: An electrochemiluminescent (ECL) swimmer driven by bipolar electrochemistry is reported for enzymatic glucose sensing. The chemo-mechanical motion induced localized hydrogen bubble generation. concomitant oxidation of the luminophore and enzymatically-produced NADH leads to ECL emission with a direct glucose-dependent light intensity. We demonstrate herein local sensing reporting in concentration gradient explored swimmer. Such dynamic approach combines synergetic way wireless propulsion selectivity using as readout method at level moving objects.

参考文章(34)
Kathrin E. Peyer, Soichiro Tottori, Famin Qiu, Li Zhang, Bradley J. Nelson, Magnetic Helical Micromachines Chemistry: A European Journal. ,vol. 19, pp. 28- 38 ,(2013) , 10.1002/CHEM.201203364
Nurhan E. Tokel, Allen J. Bard, Electrogenerated chemiluminescence. IX. Electrochemistry and emission from systems containing tris(2,2'-bipyridine)ruthenium(II) dichloride Journal of the American Chemical Society. ,vol. 94, pp. 2862- 2863 ,(1972) , 10.1021/JA00763A056
Laurent Bouffier, Thomas Doneux, Bertrand Goudeau, Alexander Kuhn, Imaging redox activity at bipolar electrodes by indirect fluorescence modulation. Analytical Chemistry. ,vol. 86, pp. 3708- 3711 ,(2014) , 10.1021/AC500623V
Kwok-Fan Chow, François Mavré, John A. Crooks, Byoung-Yong Chang, Richard M. Crooks, A large-scale, wireless electrochemical bipolar electrode microarray. Journal of the American Chemical Society. ,vol. 131, pp. 8364- 8365 ,(2009) , 10.1021/JA902683F
Milena Milutinovic, Sébastien Sallard, Dragan Manojlovic, Nicolas Mano, Neso Sojic, Glucose sensing by electrogenerated chemiluminescence of glucose-dehydrogenase produced NADH on electrodeposited redox hydrogel Bioelectrochemistry. ,vol. 82, pp. 63- 68 ,(2011) , 10.1016/J.BIOELECHEM.2011.05.005
Laurent Bouffier, Alexander Kuhn, Design of a wireless electrochemical valve. Nanoscale. ,vol. 5, pp. 1305- 1309 ,(2013) , 10.1039/C2NR32875E
Israel Rubinstein, Allen J. Bard, Electrogenerated chemiluminescence. 37. Aqueous ecl systems based on tris(2,2'-bipyridine)ruthenium(2+) and oxalate or organic acids Journal of the American Chemical Society. ,vol. 103, pp. 512- 516 ,(1981) , 10.1021/JA00393A006
Milica Sentic, Gabriel Loget, Dragan Manojlovic, Alexander Kuhn, Neso Sojic, Light-Emitting Electrochemical “Swimmers”† Angewandte Chemie. ,vol. 51, pp. 11284- 11288 ,(2012) , 10.1002/ANIE.201206227
Ambarish Ghosh, Peer Fischer, Controlled propulsion of artificial magnetic nanostructured propellers. Nano Letters. ,vol. 9, pp. 2243- 2245 ,(2009) , 10.1021/NL900186W
Maria Guix, Carmen C. Mayorga-Martinez, Arben Merkoçi, Nano/micromotors in (bio)chemical science applications. Chemical Reviews. ,vol. 114, pp. 6285- 6322 ,(2014) , 10.1021/CR400273R