Stabilization of the liquid crystalline blue phase by the addition of short-chain polystyrene

作者: Nicholas Kasch , Ingo Dierking , Michael Turner

DOI: 10.1039/C3SM00065F

关键词:

摘要: This paper examines the liquid crystalline blue phases of mixtures a readily available chiral system (consisting cholesteryl nonanoate and benzoate) with various proportions low molecular weight polydispersity polymer. By observing textures samples using polarizing optical microscopy as they are heated from nematic through phase into isotropic phase, temperature range where these is stable measured function polymer volume fraction for several weights polystyrene poly(methyl methacrylate). The showed stability up to 12 K, one largest on heating, this varied smoothly fraction. dependence could be captured well by theoretical model based Flory–Huggins Maier–Saupe theories.

参考文章(25)
N. C. Shivaprakash, M. M. M. Abdoh, Srinivasa, J. Shashidhara Prasad, Refractive Indices, Densities, Polarizabilities and Molecular Order in Cholesteric Liquid Crystals Molecular Crystals and Liquid Crystals. ,vol. 80, pp. 179- 193 ,(1982) , 10.1080/00268948208071030
Tomonori Koda, Manabu Numajiri, Susumu Ikeda, Smectic-A Phase of a Bidisperse System of Parallel Hard Rods and Hard Spheres Journal of the Physical Society of Japan. ,vol. 65, pp. 3551- 3556 ,(1996) , 10.1143/JPSJ.65.3551
Jessica Listak, Michael R. Bockstaller, Stabilization of Grain Boundary Morphologies in Lamellar Block Copolymer/Nanoparticle Blends Macromolecules. ,vol. 39, pp. 5820- 5825 ,(2006) , 10.1021/MA060778Q
F. Castles, S. M. Morris, E. M. Terentjev, H. J. Coles, Thermodynamically stable blue phases. Physical Review Letters. ,vol. 104, pp. 157801- ,(2010) , 10.1103/PHYSREVLETT.104.157801
Harry J. Coles, Mikhail N. Pivnenko, Liquid crystal ‘blue phases’ with a wide temperature range Nature. ,vol. 436, pp. 997- 1000 ,(2005) , 10.1038/NATURE03932
I. Dierking, W. Blenkhorn, E. Credland, W. Drake, R. Kociuruba, B. Kayser, T. Michael, Stabilising liquid crystalline Blue Phases Soft Matter. ,vol. 8, pp. 4355- 4362 ,(2012) , 10.1039/C2SM07155J
David C. Wright, N. David Mermin, Crystalline liquids: the blue phases Reviews of Modern Physics. ,vol. 61, pp. 385- 432 ,(1989) , 10.1103/REVMODPHYS.61.385
Alfredo Mazzulla, Gia Petriashvili, Mario Ariosto Matranga, Maria Penelope De Santo, Riccardo Barberi, Thermal and electrical laser tuning in liquid crystal blue phase I Soft Matter. ,vol. 8, pp. 4882- 4885 ,(2012) , 10.1039/C2SM25197C
P. Adamski, A. Holwek, A. Dylik-gromiec, M. Wojciechowski, Influence of Cyclohexanone Admixture on Molecular Arrangement Order S of Cholesteryl Nonanoate Molecular Crystals and Liquid Crystals. ,vol. 60, pp. 53- 63 ,(1980) , 10.1080/00268948008072424