Formation of perbromate radical anions by attachment of O− to bromate in a solid matrix
作者： J. R. Byberg
DOI: 10.1063/1.443289
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摘要: Migration of O− in x‐irradiated KClO3 crystals is exploited to study the reaction between and BrO−3 occupying anion sites KClO3. ESR spectra show that becomes attached BrO−3, forming a tetrahedral adduct BrO2−4, which virtually identical species arising from electron‐capture on BrO−4, accordance with structural equivalence [XO−3+O−] [XO−4+e−] established earlier for X = iodine aqueous solution.
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