Stability, kinetics, and magic numbers of Si+n (n=7–45) clusters

作者: J. C. Phillips

DOI: 10.1063/1.449193

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摘要: Mass spectrum maxima of Si+n clusters recently measured by Bloomfield, Freeman, and Brown are discussed in terms cluster geometries they inferred from photofragmentation branching ratios additional proposed here. Critical slowing formation kinetics for n near 10 is explained a configuration coordinate model. The critical arises the same factors thought to be responsible network glass bulk. Specifically, can described as smallest ‘‘glass’’ known.

参考文章(17)
F.E. Luborsky, Chapter 1 – Amorphous metallic alloys Amorphous Metallic Alloys. pp. 1- 7 ,(1983) , 10.1016/B978-0-408-11030-3.50006-6
F. Wooten, D. Weaire, Generation of random network models with periodic boundary conditions Journal of Non-Crystalline Solids. ,vol. 64, pp. 325- 334 ,(1984) , 10.1016/0022-3093(84)90186-8
J. M. Soler, N. García, O. Echt, K. Sattler, E. Recknagel, Microcluster Growth: Transition from Successive Monomer Addition to Coagulation Physical Review Letters. ,vol. 49, pp. 1857- 1860 ,(1982) , 10.1103/PHYSREVLETT.49.1857
M.Y. Chou, Andrew Cleland, Marvin L. Cohen, Total energies, abundances, and electronic shell structure of lithium, sodium, and potassium clusters Solid State Communications. ,vol. 52, pp. 645- 648 ,(1984) , 10.1016/0038-1098(84)90725-7
Shechao Feng, M. F. Thorpe, E. Garboczi, Effective-medium theory of percolation on central-force elastic networks. Physical Review B. ,vol. 31, pp. 276- 280 ,(1985) , 10.1103/PHYSREVB.31.276
Mark Stevens, J. Grothaus, P. Boolchand, J. Gonzalez Hernandez, Universal structural phase transition in network glasses Solid State Communications. ,vol. 47, pp. 199- 202 ,(1983) , 10.1016/0038-1098(83)90709-3
I. A. Harris, R. S. Kidwell, J. A. Northby, Structure of Charged Argon Clusters Formed in a Free Jet Expansion Physical Review Letters. ,vol. 53, pp. 2390- 2393 ,(1984) , 10.1103/PHYSREVLETT.53.2390
Shechao Feng, Pabitra N. Sen, Percolation on Elastic Networks: New Exponent and Threshold Physical Review Letters. ,vol. 52, pp. 216- 219 ,(1984) , 10.1103/PHYSREVLETT.52.216
M.F. Thorpe, Continuous deformations in random networks Journal of Non-crystalline Solids. ,vol. 57, pp. 355- 370 ,(1983) , 10.1016/0022-3093(83)90424-6
O. Echt, K. Sattler, E. Recknagel, Magic Numbers for Sphere Packings: Experimental Verification in Free Xenon Clusters Physical Review Letters. ,vol. 47, pp. 1121- 1124 ,(1981) , 10.1103/PHYSREVLETT.47.1121