The chemistry of simple ceramic glazes—III. A MASNMR study of simulated feldspars and their reactions with CaO, SrO, BaO or Li2O on heating to 1300°C
作者： Arvind-Pal S. Mandair , William R. McWhinnie
DOI: 10.1016/S0277-5387(00)83547-0
关键词:
摘要: Abstract The influence of additions CaO, SrO, BaO or Li 2 O to a synthetic albite feldspar glass was investigated by 29 Si, 27 Al and 23 Na MASNMR spectroscopy. All oxides induce more ordering the “SiO 4 ”, “AlO ” tetrahedra in when present greater (CaO > 60 mol % relative SiO ) lesser (Li 30 %) proportions. Larger CaO (80, 100 induced crystallization calcium silicate phases but similar SrO stabilized phase. data suggested that large caused separation an aluminate phase; also revealed presence octahedral 3+ sites for all MO (M = Ca, Sr, Ba), however, no aluminium seen LiO . apparent chemical shift generally moved lower field as proportion increased.
elsevier.com
sci-hub.se 参考文章(11)
Arvind-Pal S. Mandair, Paul J. Michael, William R. McWhinnie, 29Si MASNMR investigations of the thermochemistry of laponite and hectorite Polyhedron. ,vol. 9, pp. 517- 525 ,(1990) , 10.1016/S0277-5387(00)86228-2
Paul J. Michael, William R. McWhinnie, Mössbauer and esr studies of the thermochemistry of illite and montmorillonite Polyhedron. ,vol. 8, pp. 2709- 2718 ,(1989) , 10.1016/S0277-5387(00)80443-X
E. Lippmaa, M. Maegi, A. Samoson, G. Engelhardt, A. R. Grimmer, Structural studies of silicates by solid-state high-resolution silicon-29 NMR Journal of the American Chemical Society. ,vol. 102, pp. 4889- 4893 ,(1980) , 10.1021/JA00535A008
Nassif J. Ali, Peter A. Gillespie, William R. Mcwhinnie, The chemistry of simple ceramic glazes—I. 57Fe Mössbauer studies of iron-containing glazes and glasses Polyhedron. ,vol. 9, pp. 999- 1007 ,(1990) , 10.1016/S0277-5387(00)84304-1
Arvind-Pal S. Mandair, William R. McWhinnie, The chemistry of ceramic glazes—II. The influence of the presence of the oxides Na2O, CaO or Al2O3 on the thermolysis of laponite. 29Si, 23Na and 27Al MASNMR studies Polyhedron. ,vol. 9, pp. 1709- 1716 ,(1990) , 10.1016/S0277-5387(00)83976-5
Joseph V. Smith, C. Scott Blackwell, Guy L. Hovis, NMR of albite–microcline series Nature. ,vol. 309, pp. 140- 142 ,(1984) , 10.1038/309140A0
Nathan Janes, Eric Oldfield, Prediction of silicon-29 nuclear magnetic resonance chemical shifts using a group electronegativity approach: applications to silicate and aluminosilicate structures Journal of the American Chemical Society. ,vol. 107, pp. 6769- 6775 ,(1985) , 10.1021/JA00310A004
Eric Oldfield, R. James Kirkpatrick, Karen Ann Smith, Robert A. Kinsey, Donald M. Henderson, High resolution solid-state sodium-23, aluminum-27, and silicon-29 nuclear magnetic resonance spectroscopic reconnaissance of alkali and plagioclase feldspars American Mineralogist. ,vol. 70, pp. 106- 123 ,(1985)
Barbara L. Sherriff, J. Stephen Hartman, Solid-state high-resolution 29 Si NMR of feldspars; Al-Si disorder and the effects of paramagnetic centres Canadian Mineralogist. ,vol. 23, pp. 205- 212 ,(1985)
Mark Taylor, Gordon E. Brown, Structure of mineral glasses—I. The feldspar glasses NaAlSi3O8, KAlSi3O8, CaAl2Si2O8 Geochimica et Cosmochimica Acta. ,vol. 43, pp. 61- 75 ,(1979) , 10.1016/0016-7037(79)90047-4