Novel Nanocomposite Hydrogels Consisting of C‐Dots with Excellent Mechanical Properties

作者: Meng Hu , Yu Yang , Xiaoyu Gu , Yang Hu , Zhenshan Du

DOI: 10.1002/MAME.201500141

关键词:

摘要: Polyacrylamide (PAM)/carbon nanodot (C-dot) nanocomposite (NC) hydrogels were successfully prepared by free radical polymerization using C-dots as cross-linkers. The storage modulus and the cross-link density of NC compared with pure PAM hydrogel greatly enhanced due to strong hydrogen bonding interactions between C-dots. swelling ratio increased increasing C-dot contents. fracture strength PAM/C-dot was 47.5 kPa at a stretch 2940% when content 1 wt%. are an ideal nanomaterial for preparation novel excellent mechanical properties.

参考文章(48)
Huai-yin Ren, Meifang Zhu, Kazutoshi Haraguchi, Characteristic Swelling–Deswelling of Polymer/Clay Nanocomposite Gels Macromolecules. ,vol. 44, pp. 8516- 8526 ,(2011) , 10.1021/MA201272J
Zhibing Hu, Yuanye Chen, Changjie Wang, Yindong Zheng, Yong Li, Polymer gels with engineered environmentally responsive surface patterns Nature. ,vol. 393, pp. 149- 152 ,(1998) , 10.1038/30205
Eddie Wang, Malav S. Desai, Seung-Wuk Lee, Light-Controlled Graphene-Elastin Composite Hydrogel Actuators Nano Letters. ,vol. 13, pp. 2826- 2830 ,(2013) , 10.1021/NL401088B
Kazutoshi Haraguchi, Huan-jun Li, Huai-yin Ren, Meifang Zhu, Modification of Nancomposite Gels by Irreversible Rearrangement of Polymer/Clay Network Structure through Drying Macromolecules. ,vol. 43, pp. 9848- 9853 ,(2010) , 10.1021/MA102118B
Guoyi Cao, Yang Chen, Yun Ma, Yanqin Huang, Xiangmei Liu, Wenjuan Xu, Qiang Zhao, Wei Huang, Shujuan Liu, Weili Qiao, Smart Poly(N-isopropylacrylamide) Containing Iridium(III) Complexes as Water-Soluble Phosphorescent Probe for Sensing and Bioimaging of Homocysteine and Cysteine Macromolecular Rapid Communications. ,vol. 34, pp. 81- 86 ,(2013) , 10.1002/MARC.201200589
Paul Calvert, Hydrogels for Soft Machines Advanced Materials. ,vol. 21, pp. 743- 756 ,(2009) , 10.1002/ADMA.200800534
Jun Yang, Chun-rui Han, Feng Xu, Run-cang Sun, Simple approach to reinforce hydrogels with cellulose nanocrystals. Nanoscale. ,vol. 6, pp. 5934- 5943 ,(2014) , 10.1039/C4NR01214C
Fu Wang, Zheng Xie, Hao Zhang, Chun-yan Liu, Ying-ge Zhang, Highly Luminescent Organosilane‐Functionalized Carbon Dots Advanced Functional Materials. ,vol. 21, pp. 1027- 1031 ,(2011) , 10.1002/ADFM.201002279
Yu Zhao, Tasuku Nakajima, Jing Jing Yang, Takayuki Kurokawa, Jian Liu, Jishun Lu, Shuji Mizumoto, Kazuyuki Sugahara, Nobuto Kitamura, Kazunori Yasuda, A. U. D. Daniels, Jian Ping Gong, Proteoglycans and glycosaminoglycans improve toughness of biocompatible double network hydrogels. Advanced Materials. ,vol. 26, pp. 436- 442 ,(2014) , 10.1002/ADMA.201303387