Phase transformation and microstructural development of zirconia/stainless steel bonded with a Ti/Ni/Ti interlayer for the potential application in solid oxide fuel cells

作者: Shen-Hung Wei , Chien-Cheng Lin

DOI: 10.1557/JMR.2014.65

关键词:

摘要: The 8 mol% yttria-stabilized zirconia (8Y-ZrO2) was bonded to stainless steel 316L at 900 °C for 1 h in a protective Ar atmosphere using an interlayer of Ti/Ni/Ti. Interfacial microstructures were characterized both secondary electron microscope (SEM) and transmission (TEM), each with attached energy dispersive spectroscope (EDS). A layer sequence r-phase/TiFe2/TiFe b-Ti/Ti2Fe observed the 316L/Ti interface, whereas Ti2Ni/Ti2Ni TiNi/TiNi3 found Ti/Ni interface. Furthermore, TiO c-ZrO2� x formed Ti/8Y-ZrO2 An acicular a-Ti fine x-phase existed along b-Ti residual Ti foil adjacent 316L, but Ti2Ni within other 8Y-ZrO2. orientation relationships � ½� == 111 ðÞ 0001 , respectively. microstructural development elucidated aid Fe–Ti Ni–Ti binary phase diagrams.

参考文章(43)
博明 岡本, Phase diagrams of binary iron alloys ASM International. ,(1993)
Rongfa Chen, Dunwen Zuo, Min Wang, Improvement of Joint Strength of SiCp/Al Metal Matrix Composite in Transient Liquid Phase Bonding Using Cu/Ni/Cu Film Interlayer Journal of Materials Science & Technology. ,vol. 22, pp. 291- 294 ,(2009)
W.Z. Zhu, S.C. Deevi, Development of interconnect materials for solid oxide fuel cells Materials Science and Engineering A-structural Materials Properties Microstructure and Processing. ,vol. 348, pp. 227- 243 ,(2003) , 10.1016/S0921-5093(02)00736-0
Arnold S. Grot, Joseph E. Spruiell, Microstructural stability of titanium-modified type 316 and type 321 stainless steel Metallurgical and Materials Transactions A-physical Metallurgy and Materials Science. ,vol. 6, pp. 2023- 2030 ,(1975) , 10.1007/BF03161827
M. Nishida, C. M. Wayman, T. Honma, Precipitation processes in near-equiatomic TiNi shape memory alloys Metallurgical and Materials Transactions A-physical Metallurgy and Materials Science. ,vol. 17, pp. 1505- 1515 ,(1986) , 10.1007/BF02650086
X. M. Xue, J. T. Wang, Z. T. Sui, Wettability and interfacial reaction of alumina and zirconia by reactive silver-indium base alloy at mid-temperatures Journal of Materials Science. ,vol. 28, pp. 1317- 1322 ,(1993) , 10.1007/BF01191971
Karl A. Gschneidner, Mary Verkade, Electronic and crystal structures, size (ECS2) model for predicting binary solid solutions Progress in Materials Science. ,vol. 49, pp. 411- 428 ,(2004) , 10.1016/S0079-6425(03)00026-4
M Ghosh, K Bhanumurthy, G.B Kale, J Krishnan, S Chatterjee, Diffusion bonding of titanium to 304 stainless steel Journal of Nuclear Materials. ,vol. 322, pp. 235- 241 ,(2003) , 10.1016/J.JNUCMAT.2003.07.004
J. C. Williams, B. S. Hickman, D. H. Leslie, The effect of ternary additions on the decompositon of metastable beta-phase titanium alloys Metallurgical Transactions. ,vol. 2, pp. 477- 484 ,(1971) , 10.1007/BF02663337
C. H. Cheng, Y. W. Chang, C. W. Hong, Multiscale Parametric Studies on the Transport Phenomenon of a Solid Oxide Fuel Cell Journal of Fuel Cell Science and Technology. ,vol. 2, pp. 219- 225 ,(2005) , 10.1115/1.2039950