Glass formation in the Sb2O3–CdCl2–SrCl2 ternary system
作者： M. Iezid , M. Legouera , F. Goumeidane , M. Poulain , V. Nazabal
DOI: 10.1016/J.JNONCRYSOL.2011.04.002
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摘要: Abstract Vitreous systems based on antimony oxide Sb 2 O 3 have been investigated. The limits for glass formation are reported in the –CdCl –SrCl ternary system, and –(0.5CdCl + 0.5ZnCl ) pseudo system. Amorphous state is confirmed by XRD patterns. Thermal measurements implemented differential scanning calorimetry show that Tg above 300 °C. As a general trend, increases with chloride content. These glasses an extended transmission mid-infrared spectrum refractive index larger than 2. influence of CdCl /Sb substitution physical properties has studied (90 − x)Sb –xCdCl –10SrCl system: thermal expansion, Vickers microhardness, Young bulk modulus decrease as cadmium concentration increases. An inverse dependence observed shear modulus. This behaviour discussed relation to structural hypothesis.
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