The interface between a metal and an electrolytic solution

摘要: Abstract Measurements of the capacity electrical double layer at interface between a polarizable mercury electrode and an aqueous solution strong electrolyte are interpreted theoretically. Attention is concentrated on charges actual phase boundary, whose behaviour has not been satisfactorily explained before. It suggested that for anodic polarization increasing number atoms situated adsorbed sites otherwise flat surface. These carry charge, lead to rise in measured as becomes anodic. thus shown why function form fluoride electrolytes, where there no specific adsorption anion, so similar other is. The water molecules contact with considered some detail, compared bulk monolayer tha...