The influence of operating conditions on the formation of soot and hydrocarbons in flames

作者: HEINZ GEORG. WAGNER

DOI: 10.1089/HWM.1994.11.5

关键词:

摘要: Technical devices for the combustion of hydrocarbons with air are usually designed in a way that they exhibit high reliability and efficiency. The efficiency is computed from thermodynamic considerations, assuming products hydrocarbon-air mixtures CO{sub 2} H{sub 2}O takes place stoichiometric mixtures. Real systems, however, deviate more or less assumption their exhaust may contain CO, traces like PAH aldehydes other substances. There many different use, simple gas oil burners house heating to complicated ones power stations, chambers, e.g., jet engines piston engines. In order achieve (relatively) save operation, most these operate diffusion flames at least some participation flames. 42 refs., 12 figs., 1 tab.

参考文章(14)
H. W. Kroto, J. R. Heath, S. C. O’Brien, R. F. Curl, R. E. Smalley, C 60 : Buckminsterfullerene Nature. ,vol. 318, pp. 162- 163 ,(1985) , 10.1038/318162A0
J.H. kent, H.Gg. Wagner, Who do Diffusion flames Emit smoke Combustion Science and Technology. ,vol. 41, pp. 245- 269 ,(1984) , 10.1080/00102208408923834
Jack B. Howard, J. Thomas McKinnon, Yakov Makarovsky, Arthur L. Lafleur, M. Elaine Johnson, Fullerenes C60 and C70 in flames. Nature. ,vol. 352, pp. 139- 141 ,(1991) , 10.1038/352139A0
R. LONG, E. E. TOMPKINS, Formation of Polycyclic Aromatic Hydrocarbons in Pre-mixed Acetylene–Oxygen Flames Nature. ,vol. 213, pp. 1011- 1012 ,(1967) , 10.1038/2131011A0
STEPHEN J. Harris, IAN M. Kennedy, The Coagulation of Soot Particles with van der Waals Forces Combustion Science and Technology. ,vol. 59, pp. 443- 454 ,(1988) , 10.1080/00102208808947110
J.H. Kent, S.J. Bastin, Parametric effects on sooting in turbulent acetylene diffusion flames Combustion and Flame. ,vol. 56, pp. 29- 42 ,(1984) , 10.1016/0010-2180(84)90003-8
P. Roumeliotis, W. Liebald, K. K. Unger, Determination of Phenols from Automobile Exhaust by Means of High-Performance Liquid Chromatography (HPLC) International Journal of Environmental Analytical Chemistry. ,vol. 9, pp. 27- 43 ,(1981) , 10.1080/03067318108071507
H.A. Becker, D. Liang, Total emission of soot and thermal radiation by free turbulent diffusion flames Combustion and Flame. ,vol. 44, pp. 305- 318 ,(1982) , 10.1016/0010-2180(82)90080-3
K. H. Homann, Ch. Wellmann, Arrhenius Parameters for the Reactions of O Atoms with Some Alkynes in the Range 300-1300 K Berichte der Bunsengesellschaft für physikalische Chemie. ,vol. 87, pp. 527- 532 ,(1983) , 10.1002/BBPC.19830870614
Russell E. Duff, S. H. Bauer, Equilibrium Composition of the C/H System at Elevated Temperatures Journal of Chemical Physics. ,vol. 36, pp. 1754- 1767 ,(1962) , 10.1063/1.1701262