Thermodynamic properties of actinide complexes. II. Thorium(IV)-acetate system
作者： R. Portanova , P. Di Bernardo , O. Traverso , G.A. Mazzocchin , L. Magon
DOI: 10.1016/0022-1902(75)80853-0
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摘要: The changes in free energy, enthalpy and entropy for the formation of thorium(IV)--acetate complexes have been determined at 25/sup 0/C 1.00 M aqueous perchlorate-medium. All five formed, are found to be stabilized by a large gain entropy. marked increase values ..delta..H/sub j/ ..delta..S/sub j/, relative third step complexation has explained terms coordination change.
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