A review on synthesis, crystal structure and functionality of naphthalenedicarboxylate ligated metal-organic frameworks
作者： Kranthi Kumar Gangu , Suresh Maddila , Sreekantha B. Jonnalagadda
DOI: 10.1016/J.ICA.2017.06.038
关键词:
摘要: Abstract For the past 20 years, metal-organic frameworks (MOFs) have been appealing to material scientists due their unique properties and varied applications. MOFs are built using metal ions selected organic ligands/linkers, viz. multidentate carboxylates, N-containing heterocyclic compounds, etc. The of naphthalenedicarboxylate (NDC) ligands, such as flexibility, viable coordination modes, bulkiness good ligation nature sequester in different orientations make them particularly attractive for synthesis MOFs. two carboxylate groups present NDC ligand promote various which prompt diverse MOF structures with porosity. ligands ions, mostly Zn(II), Cd(II), Mn(II), Co(II), Ag(I) lanthanides created networks topologies, innovative applications fields gas storage, separation, luminescence, catalysis, drug delivery magnetism. choice precursors, reaction environment including temperature, metal/ligand ratio, solvent, pH, can profoundly affect architecture quantitatively influence probable virtues led extensive adoption fields. This review provides a comprehensive insight into design
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