Dominated Effect Analysis of the Channel Size of Silica Support Materials on the Catalytic Performance of Immobilized Lipase Catalysts in the Transformation of Unrefined Waste Cooking Oil to Biodiesel
作者： Haidong Zhang , Yu Zou , Yu Shen , Xue Gao , Xuxu Zheng
DOI: 10.1007/S12155-014-9492-Y
关键词:
摘要: Three mesoporous silica materials with various channel sizes and structures were employed to prepare immobilized lipase catalysts for the transesterification of unrefined wasted cooking oil (UWCO) biodiesel at room temperature. The size support material was found be key point obtain high initial specific activity sustainability catalysts. A SBA-15 appropriate (14.0 nm) demonstrates best capacity lipase. catalyst shows much higher than a MCM-41 (channel 1.8 nm) mesostructured cellular foam (MCF) 28.0 nm) as in transformation UWCO biodiesel. After 60 h reaction 28 °C, fatty acid methyl ester (FAME) yield up 80.1 71.8 % can achieved using SBA-15-immobilized
springer.com
cabdirect.org
sci-hub.se 参考文章(36)
Jie Fan, Jie Lei, Limin Wang, Chengzhong Yu, Bo Tu, Dongyuan Zhao, Rapid and high-capacity immobilization of enzymes based on mesoporous silicas with controlled morphologies. Chemical Communications. ,vol. 17, pp. 2140- 2141 ,(2003) , 10.1039/B304391F
Ganesh L. Maddikeri, Aniruddha B. Pandit, Parag R. Gogate, Intensification Approaches for Biodiesel Synthesis from Waste Cooking Oil: A Review Industrial & Engineering Chemistry Research. ,vol. 51, pp. 14610- 14628 ,(2012) , 10.1021/IE301675J
B. Pauwels, G. Van Tendeloo, C. Thoelen, W. Van Rhijn, P. A. Jacobs, Structure Determination of Spherical MCM‐41 Particles Advanced Materials. ,vol. 13, pp. 1317- 1320 ,(2001) , 10.1002/1521-4095(200109)13:17<1317::AID-ADMA1317>3.0.CO;2-5
Ying Wan, Zhao, On the Controllable Soft-Templating Approach to Mesoporous Silicates Chemical Reviews. ,vol. 107, pp. 2821- 2860 ,(2007) , 10.1021/CR068020S
An-Fei Hsu, Kerby C. Jones, Thomas A. Foglia, William N. Marmer, Continuous production of ethyl esters of grease using an immobilized lipase Journal of the American Oil Chemists' Society. ,vol. 81, pp. 749- 752 ,(2004) , 10.1007/S11746-004-0973-9
Dongyuan Zhao, Qisheng Huo, Jianglin Feng, Bradley F. Chmelka, Galen D. Stucky, Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermally Stable, Mesoporous Silica Structures Journal of the American Chemical Society. ,vol. 120, pp. 6024- 6036 ,(1998) , 10.1021/JA974025I
Amit Katiyar, Lei Ji, Panagiotis Smirniotis, Neville G. Pinto, Protein adsorption on the mesoporous molecular sieve silicate SBA-15: effects of pH and pore size. Journal of Chromatography A. ,vol. 1069, pp. 119- 126 ,(2005) , 10.1016/J.CHROMA.2004.10.077
Zexue DU, Zhong TANG, Haijing WANG, Jianli ZENG, Yanfeng CHEN, Enze MIN, Research and development of a sub-critical methanol alcoholysis process for producing biodiesel using waste oils and fats Chinese Journal of Catalysis. ,vol. 34, pp. 101- 115 ,(2013) , 10.1016/S1872-2067(11)60490-7
D. Zhao, Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores Science. ,vol. 279, pp. 548- 552 ,(1998) , 10.1126/SCIENCE.279.5350.548
W. H. Wu, T. A. Foglia, W. N. Marmer, J. G. Phillips, Optimizing production of ethyl esters of grease using 95% ethanol by response surface methodology Journal of the American Oil Chemists' Society. ,vol. 76, pp. 517- 521 ,(1999) , 10.1007/S11746-999-0034-2