Photoluminescence of thin films ZrO2 : Er3+ excited by soft X-ray
作者： Lee-Jene Lai , Tieh-Chi Chu , Meng-I Lin , Yao-Kwang Lin
DOI: 10.1016/J.SSC.2007.08.028
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摘要: Abstract The photoluminescence (PL) properties and crystalline structure of undoped erbium ion (Er 3+ )-doped zirconia (ZrO 2 ) that were prepared by sol–gel methods examined. ZrO films exhibited a dopant concentration-dependent phase. As the Er ions’ concentration increases, amount monoclinic phases declines. However, proportion tetragonal phase is enhanced. This fact suggests ions replace Zr 4+ cause transition in host lattice . Photoluminescence bands observed exciting film at 300 eV with soft X-rays. Experimental results showed PL emission +3 -doped can be tuned controlling concentration. In particular, increasing concentration, blue are quenched whereas green red phenomenon explained as non-radiative energy transfer.
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E De la Rosa-Cruz, LA Dıaz-Torres, RA Rodrıguez-Rojas, MA Meneses-Nava, O Barbosa-Garcıa, P Salas, None, Luminescence and visible upconversion in nanocrystalline ZrO2:Er3+ Applied Physics Letters. ,vol. 83, pp. 4903- 4905 ,(2003) , 10.1063/1.1632020
E. De la Rosa-Cruz, L. A. Diaz-Torres, P. Salas, R. A. Rodrı́guez, G. A. Kumar, M. A. Meneses, J. F. Mosiño, J. M. Hernández, O. Barbosa-Garcı́a, Luminescent properties and energy transfer in ZrO2:Sm3+ nanocrystals Journal of Applied Physics. ,vol. 94, pp. 3509- 3515 ,(2003) , 10.1063/1.1599960
Lee-Jene Lai, Ching-Shen Su, THERMOLUMINESCENCE OF ZRO2 DOPED WITH ER2O3 INDUCED BY ULTRAVIOLET AND X-RAY RADIATION Journal of Applied Physics. ,vol. 85, pp. 8362- 8365 ,(1999) , 10.1063/1.370683
Marco Kirm, Jaan Aarik, Meelis Jürgens, Ilmo Sildos, Thin films of HfO2 and ZrO2 as potential scintillators Nuclear Instruments & Methods in Physics Research Section A-accelerators Spectrometers Detectors and Associated Equipment. ,vol. 537, pp. 251- 255 ,(2005) , 10.1016/J.NIMA.2004.08.020
A. S. Kao, G. L. Gorman, Modification of zirconia film properties by low‐energy ion bombardment during reactive ion‐beam deposition Journal of Applied Physics. ,vol. 67, pp. 3826- 3834 ,(1990) , 10.1063/1.345030
R. I. Merino, J. A. Pardo, J. I. Peña, G. F. de la Fuente, A. Larrea, V. M. Orera, Luminescence properties of ZrO 2 − C a O eutectic crystals with ordered lamellar microstructure activated with Er 3 + ions Physical Review B. ,vol. 56, pp. 10907- 10915 ,(1997) , 10.1103/PHYSREVB.56.10907
E Pereyra-Perea, M R Estrada-Yañez, M García, Preliminary studies on luminescent terbium-doped thin films prepared by the sol - gel process Journal of Physics D. ,vol. 31, ,(1998) , 10.1088/0022-3727/31/3/001
L.J. Lai, P.C. Tseng, Y.W. Yang, S.C. Chung, Y.F. Song, N.F. Cheng, C.C. Chen, C.T. Chen, K.L. Tsang, Current status of the wide-range (10–1500eV) spherical grating monochromator beamline at SRRC Nuclear Instruments & Methods in Physics Research Section A-accelerators Spectrometers Detectors and Associated Equipment. pp. 586- 588 ,(2001) , 10.1016/S0168-9002(01)00418-1
Ana E. Bohé, Julio Andrade-Gamboa, Daniel M. Pasquevich, Alfredo J. Tolley, Jorge L. Pelegrina, Microstructural Characterization of ZrO2 Particles Prepared by Reaction of Gaseous ZrCl4 with Fe2O3 Journal of the American Ceramic Society. ,vol. 83, pp. 755- 760 ,(2004) , 10.1111/J.1151-2916.2000.TB01270.X
Marc Mamak, Neil Coombs, Geoffrey A. Ozin, Mesoporous Nickel−Yttria−Zirconia Fuel Cell Materials Chemistry of Materials. ,vol. 13, pp. 3564- 3570 ,(2001) , 10.1021/CM001259J