A Dinuclear Ruthenium(II) Chelating Amido Complex: Synthesis, Characterization, and Coupling Reaction with Carbon Monoxide
作者： Shin Takemoto , Shinya Oshio , Tomoharu Kobayashi , Hiroyuki Matsuzaka , Masatsugu Hoshi
DOI: 10.1021/OM049704Y
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摘要: [Cp*RuCl]4 (Cp* = η5-C5Me5) reacts with 2 equiv of dilithium 2,3-naphthalenediamide to afford the dinuclear bridging amido complex [(Cp*Ru)2{μ2-(NH)2C10H6}] (1b) in moderate yield. Treatment 1b CO (1 atm) resulted incorporation three molecules into diruthenium core give carbamoyl bis(carbonyl) [Cp*Ru(μ2-CO){μ2-2,3-(CONH)(NH)C10H6}RuCp*(CO)] (4).
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