Spectrophotofluorescent and spectrophotophosphorescent data on insecticidal carbamates and the analysis of five carbamates in milk by spectrophotofluorometry

摘要: The use of spectrophotofluorometry (SPF) and spectrophotophosphorimetry (SPP) for residue analyses has been limited. macdougall (1962 1964) reviewed the fluorescence pesticide analysis suggested other areas in which SPF might be applicable. In addition to material covered these reviews, hydrolysis followed by applied determination Zinophos® (O,O-diethyl O-2-pyrazinyl phosphorothioate) soil plant tissues (KIIGEMAGI TERRIERE 1963), azinphosmethyl [Guthion®, O,O-dimethyl S-4-oxo-l,2,3-benzotriazin-3 (4H) -ylmethyl phosphorodithioate] milk animal (LOEFFLER et al. 1966, ADAMS ANDERSON 1966), Maretin (N-hydroxynaphthalimide diethyl phosphate) (ANDERSON 1966). A fluorometric method methyl paraoxon (dimethyl p-nitrophenyl published (SKURIC 1965). a comparison analytical techniques detection five carbamate insecticides, EBERLE GUNTHER (1965) included as can used determine carbaryl Zectran®1 after hydrolysis. KNAAK aqueous solutions its metabolites although they reported that showed no some organic solvents.