Transition metal ions in glasses: Network modifiers or quasi-molecular complexes?
作者： Carolynn Nelson , Toshiharu Furukawa , William B. White
DOI: 10.1016/0025-5408(83)90007-7
关键词:
摘要: Abstract Transition metal ions dissolve in silicate, phosphate, and borate glasses as molecular units, quasi-molecular complexes, occupants of large, framework structure-controlled sites depending on size ionic charge. Raman spectra optical absorption support this hypothesis offer a new interpretation for the assignment certain transition to tetrahedral glass structure.
elsevier.com
sci-hub.se 参考文章(13)
C. Austen Angell, Joe Wong, Glass : structure by spectroscopy M. Dekker. ,(1976)
W.L. Konijnendijk, J.H.J.M. Buster, Raman-scattering measurements on silicate glasses containing AsO43− ions Journal of Non-crystalline Solids. ,vol. 22, pp. 379- 389 ,(1976) , 10.1016/0022-3093(76)90067-3
Carolynn Nelson, William B White, Transition metal ions in silicate melts—I. Manganese in sodium silicate melts Geochimica et Cosmochimica Acta. ,vol. 44, pp. 887- 893 ,(1980) , 10.1016/0016-7037(80)90269-0
J. Wong, Vibrational spectra of vapor-deposited binary phosphosilicate glasses Journal of Non-crystalline Solids. ,vol. 20, pp. 83- 100 ,(1976) , 10.1016/0022-3093(76)90109-5
Harry G. Hecht, Study of the Structure of Nickel in Soda—Boric Oxide Glasses The Journal of Chemical Physics. ,vol. 47, pp. 1840- 1843 ,(1967) , 10.1063/1.1712177
Steven A. Brawer, William B. White, Raman spectroscopic study of hexavalent chromium in some silicate and borate glasses Materials Research Bulletin. ,vol. 12, pp. 281- 287 ,(1977) , 10.1016/0025-5408(77)90146-5
R. E. Tischer, Effect of Compression and Compositional Changes on the Nature of Chromium Sites in Simple Glasses Journal of Chemical Physics. ,vol. 48, pp. 4291- 4299 ,(1968) , 10.1063/1.1669771
R. J. Landry, J. T. Fournier, C. G. Young, Electron Spin Resonance and Optical Absorption Studies of Cr3+ in a Phosphate Glass The Journal of Chemical Physics. ,vol. 46, pp. 1285- 1290 ,(1967) , 10.1063/1.1840846
W.L. Konijnendijk, J.M. Stevels, The structure of borosilicate glasses studied by Raman scattering Journal of Non-crystalline Solids. ,vol. 20, pp. 193- 224 ,(1975) , 10.1016/0022-3093(76)90132-0
Steven A. Brawer, William B. White, Structure and crystallization behaviour of Li2O-Fe2O3-SiO2 glasses Journal of Materials Science. ,vol. 13, pp. 1907- 1920 ,(1978) , 10.1007/BF00552897