Preparation and characterization of poly(vinyl chloride) calcium carbonate nanocomposites via melt intercalation
作者： C. B. Patil , U. R. Kapadi , D. G. Hundiwale , P. P. Mahulikar
DOI: 10.1007/S10853-009-3414-Y
关键词:
摘要: Calcium carbonate was synthesized by in situ deposition technique and its nano size (35–60 nm) confirmed transmission electron microscopy (TEM). Composites of the filler CaCO3 (micro nano) matrix poly(vinyl chloride) (PVC) were prepared with different loadings (0–5 wt%) melt intercalation. Brabender torque rheometer equipped an internal mixer has been used for preparation formulations composites. The effect content both nano- micro level on nanostructure properties is reported here. nanostructures studied wide angle X-ray diffraction scanning microscopy. mechanical, thermal, dynamic mechanical PVC/micro- nano-CaCO3 composites characterized using universal testing machine, thermogravimetric analyzer, analyzer. results thermal analysis indicated that stability PVC/nano-CaCO3 improved as compared corresponding microcomposites, pristine PVC maximum improvement obtained at 1 3 phr loadings. However, tensile strength decreased significantly increase loading micro-CaCO3, whereas storage modulus glass transition temperature increased significantly.
springer.com
harvard.edu
sci-hub.se 参考文章(31)
Liu Ling, Meng Qing-han, Electrochemical properties of mesoporous carbon aerogel electrodes for electric double layer capacitors Journal of Materials Science. ,vol. 40, pp. 4105- 4107 ,(2005) , 10.1007/S10853-005-0644-5
Yong-Zhong Bao, Zhi-Ming Huang, Zhi-Xue Weng, Preparation and characterization of poly(vinyl chloride)/layered double hydroxides nanocomposite via in situ suspension polymerization Journal of Applied Polymer Science. ,vol. 102, pp. 1471- 1477 ,(2006) , 10.1002/APP.24317
Dezhen Wu, Xiaodong Wang, Yongzhi Song, Riguang Jin, Nanocomposites of poly(vinyl chloride) and nanometric calcium carbonate particles: Effects of chlorinated polyethylene on mechanical properties, morphology, and rheology Journal of Applied Polymer Science. ,vol. 92, pp. 2714- 2723 ,(2004) , 10.1002/APP.20295
T. Peprnicek, J. Duchet, L. Kovarova, J. Malac, J.F. Gerard, J. Simonik, Poly(vinyl chloride)/clay nanocomposites : X-ray diffraction, thermal and rheological behaviour Polymer Degradation and Stability. ,vol. 91, pp. 1855- 1860 ,(2006) , 10.1016/J.POLYMDEGRADSTAB.2005.11.003
S. Mishra, S. H. Sonawane, R. P. Singh, Studies on characterization of nano CaCO3 prepared by the in situ deposition technique and its application in PP‐nano CaCO3 composites Journal of Polymer Science Part B. ,vol. 43, pp. 107- 113 ,(2005) , 10.1002/POLB.20296
Hu Haiyan, Pan Mingwang, Li Xiucuo, Shi Xudong, Zhang Liucheng, Preparation and characterization of poly(vinyl chloride)/organoclay nanocomposites by in situ intercalation Polymer International. ,vol. 53, pp. 225- 231 ,(2004) , 10.1002/PI.1309
C. Saujanya, S. Radhakrishnan, Structure development and crystallization behaviour of PP/nanoparticulate composite Polymer. ,vol. 42, pp. 6723- 6731 ,(2001) , 10.1016/S0032-3861(01)00140-9
Chaoying Wan, Xiuying Qiao, Yong Zhang, Yinxi Zhang, Effect of different clay treatment on morphology and mechanical properties of PVC-clay nanocomposites Polymer Testing. ,vol. 22, pp. 453- 461 ,(2003) , 10.1016/S0142-9418(02)00126-5
Chaoying Wan, Yong Zhang, Yinxi Zhang, Effect of alkyl quaternary ammonium on processing discoloration of melt-intercalated PVC-montmorillonite composites Polymer Testing. ,vol. 23, pp. 299- 306 ,(2004) , 10.1016/J.POLYMERTESTING.2003.08.001
F. L. Gong, C. G. Zhao, M. Feng, H. L. Qin, M. S. Yang, Synthesis and characterization of PVC/montmorillonite nanocomposite Journal of Materials Science. ,vol. 39, pp. 293- 294 ,(2004) , 10.1023/B:JMSC.0000007758.00802.1A