Effect of Nb doping on preferential orientation, phase transformation behavior and electrical properties of PbZrO3 thin films
作者： Mao Ye , Qiu Sun , Xiangqun Chen , Zhaohua Jiang , Fuping Wang
DOI: 10.1016/J.JALLCOM.2012.06.116
关键词:
摘要: Abstract Undoped and Nb-doped (1, 3, 5, 7 9 mol%) PbZrO 3 antiferroelectric thin films were deposited on Pt(1 1 1)/Ti/SiO 2 /Si substrates by using a sol–gel method. All the had perovskite phase structure exhibited distinct preferential orientation, transformation behavior electrical properties, due to effect of Nb doping. On extent dopant, orientation was changed from (1 0 0) (1 1 1) gradually. Meanwhile, with increasing content, gradual change AFE ferroelectric at room temperature observed. Dielectric constant as function content also reported. The dielectric increased up 7 mol% then decreased 9 mol% Nb. loss remained quite low (less than 0.05) in whole frequency or voltage ranges.
sci-hub.se 参考文章(44)
M. Es-Souni, A. Piorra, C.-H. Solterbeck, S. Iakovlev, M. Abed, Microstructure and properties of solution deposited, Nb-doped PZT thin films Journal of Electroceramics. ,vol. 9, pp. 125- 135 ,(2002) , 10.1023/A:1022806506193
Xihong Hao, Jiwei Zhai, Xi Yao, A comprehensive investigation on the phase transformation behavior and electrical properties of (Pb1−xBax)ZrO3 (0≤x≤0.5) thin films Journal of Applied Physics. ,vol. 104, pp. 124101- ,(2008) , 10.1063/1.3041153
Jayanta Parui, S. B. Krupanidhi, Dielectric properties of (110) oriented PbZrO3 and La-modified PbZrO3 thin films grown by sol-gel process on Pt(111)∕Ti∕SiO2∕Si substrate Journal of Applied Physics. ,vol. 100, pp. 044102- ,(2006) , 10.1063/1.2234819
Xihong Hao, Jing Zhou, Shengli An, Effects of PbO Content on the Dielectric Properties and Energy Storage Performance of (Pb0.97La0.02)(Zr0.97Ti0.03)O3 Antiferroelectric Thin Films Journal of the American Ceramic Society. ,vol. 94, pp. 1647- 1650 ,(2011) , 10.1111/J.1551-2916.2011.04460.X
Da-Wei Wang, Mao-Sheng Cao, Jie Yuan, Ran Lu, Hong-Bo Li, Hai-Bo Lin, Quan-Liang Zhao, De-Qing Zhang, Effect of sintering temperature and time on densification, microstructure and properties of the PZT/ZnO nanowhisker piezoelectric composites Journal of Alloys and Compounds. ,vol. 509, pp. 6980- 6986 ,(2011) , 10.1016/J.JALLCOM.2011.03.186
Ebru Mensur Alkoy, Sedat Alkoy, Tadashi Shiosaki, Effects of Ce, Cr and Er Doping and Annealing Conditions on the Microstructural Features and Electrical Properties of PbZrO3 Thin Films Prepared by Sol-Gel Process Japanese Journal of Applied Physics. ,vol. 44, pp. 6654- 6660 ,(2005) , 10.1143/JJAP.44.6654
Naratip Vittayakorn, Banjong Boonchom, Effect of BiAlO3 modification on the stability of antiferroelectric phase in PbZrO3 ceramics prepared by conventional solid state reaction Journal of Alloys and Compounds. ,vol. 509, pp. 2304- 2310 ,(2011) , 10.1016/J.JALLCOM.2010.10.206
Wei Qin, Yiping Guo, Bing Guo, Mingyuan Gu, Dielectric and optical properties of BiFeO3–(Na0.5Bi0.5)TiO3 thin films deposited on Si substrate using LaNiO3 as buffer layer for photovoltaic devices Journal of Alloys and Compounds. ,vol. 513, pp. 154- 158 ,(2012) , 10.1016/J.JALLCOM.2011.10.011
Wai-Hung Chan, Z. Xu, T. F. Hung, Haydn Chen, Effect of La substitution on phase transitions in lead zirconate stannate titanate (55/35/10) ceramics Journal of Applied Physics. ,vol. 96, pp. 6606- 6610 ,(2004) , 10.1063/1.1805732
Cheng-Lung Hung, Tai-Bor Wu, Effects of Nb doping on highly fatigue-resistant thin films of (Pb0.8Ba0.2)ZrO3 for ferroelectric memory application Journal of Crystal Growth. ,vol. 274, pp. 402- 406 ,(2005) , 10.1016/J.JCRYSGRO.2004.10.013