[10] Calculation of simulated sedimentation velocity profiles for self-associating solutes

摘要: Publisher Summary This chapter presents the simulation procedure that is particularly suitable for rapidly equilibrating self-associations of kind first treated by Gilbert. The technique described in can be applied to velocity sedimentation ultracentrifuge. general scheme used simulate diffusion derived from developed Vink describe concentration- independent a system constant cross section. model modified deal with concentration dependence , sector shape cell, and nonuniform array box sizes. calculates flow solute across each boundary during short time interval. Once has been found, accumulation (or depletion) calculated. Dividing volume gives change A new concentrations calculated, calculation repeated. It reported as all computational methods this have number features common, detailed consideration one some further use an introduction transport processes general.