Flow-through experiments on water–rock interactions in a sandstone caused by CO2 injection at pressures and temperatures mimicking reservoir conditions
作者： Farhana Huq , Stefan B. Haderlein , Olaf A. Cirpka , Marcus Nowak , Philipp Blum
DOI: 10.1016/J.APGEOCHEM.2015.04.006
关键词:
摘要: Abstract Flow-through experiments were performed in a newly designed experimental setup to study the water–rock interactions caused by CO 2 injection sandstones obtained from Altmark natural gas reservoir under simulated conditions of 125 °C and 50 bar partial pressure. Two different sets conducted using -saturated millipore water brine (41.62 g L −1 NaCl 31.98 g L CaCl ·2H O), mimicking chemical composition formation water. The major components sandstone quartz (clasts + cement), feldspars, clay minerals (illite chlorite), cements carbonates anhydrite. Fluid analysis suggested predominant dissolution anhydrite causing increased concentrations calcium sulfate at early time periods non-equilibrium geochemical conditions. Ca/SO 4 molar ratio (>1) indicated concurrent both calcite Dissolution feldspar minor amounts (chlorite) was also evident during flow-through experiments. permeability sample factor two mostly due rock injection. Geochemical modeling suggests as buffering process system. results may future studies be used for numerical simulations predicting storage reservoirs.
core.ac.uk
harvard.edu
cabdirect.org
elsevier.com
sci-hub.se 参考文章(49)
W. D. Gunter, B. Wiwehar, E. H. Perkins, Aquifer disposal of CO2-rich greenhouse gases: Extension of the time scale of experiment for CO2-sequestering reactions by geochemical modelling Mineralogy and Petrology. ,vol. 59, pp. 121- 140 ,(1997) , 10.1007/BF01163065
Irina Gaus, Role and impact of CO2–rock interactions during CO2 storage in sedimentary rocks International Journal of Greenhouse Gas Control. ,vol. 4, pp. 73- 89 ,(2010) , 10.1016/J.IJGGC.2009.09.015
Isabelle Czernichowski-Lauriol, Chris Rochelle, Jonathan Pearce, Irina Gaus, Mohamed Azaroual, Pierre Durst, Geochemical interactions between CO2, pore-waters and reservoir rocks : lessons learned from laboratory experiments, field studies and computer simulations Springer. ,(2006)
User's guide to PHREEQC (Version 2)-a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations Water-Resources Investigations Report. ,vol. 312, ,(1999) , 10.3133/WRI994259
L. Luquot, P. Gouze, Experimental determination of porosity and permeability changes induced by injection of CO2 into carbonate rocks Chemical Geology. ,vol. 265, pp. 148- 159 ,(2009) , 10.1016/J.CHEMGEO.2009.03.028
J.M. Ketzer, R. Iglesias, S. Einloft, J. Dullius, R. Ligabue, V. de Lima, Water-rock-CO2 interactions in saline aquifers aimed for carbon dioxide storage: Experimental and numerical modeling studies of the Rio Bonito Formation (Permian), southern Brazil Applied Geochemistry. ,vol. 24, pp. 760- 767 ,(2009) , 10.1016/J.APGEOCHEM.2009.01.001
Jiemin Lu, Yousif K. Kharaka, James J. Thordsen, Juske Horita, Athanasios Karamalidis, Craig Griffith, J. Alexandra Hakala, Gil Ambats, David R. Cole, Tommy J. Phelps, Michael A. Manning, Paul J. Cook, Susan D. Hovorka, CO2–rock–brine interactions in Lower Tuscaloosa Formation at Cranfield CO2 sequestration site, Mississippi, U.S.A. Chemical Geology. ,vol. 291, pp. 269- 277 ,(2012) , 10.1016/J.CHEMGEO.2011.10.020
Volker Lüders, Birgit Plessen, Rolf L Romer, Stephan M Weise, David A Banks, Peer Hoth, Peter Dulski, Georg Schettler, None, Chemistry and isotopic composition of Rotliegend and Upper Carboniferous formation waters from the North German Basin Chemical Geology. ,vol. 276, pp. 198- 208 ,(2010) , 10.1016/J.CHEMGEO.2010.06.006
Suzanne J. T. Hangx, Christopher J. Spiers, Colin J. Peach, Mechanical behavior of anhydrite caprock and implications for CO2sealing capacity Journal of Geophysical Research. ,vol. 115, ,(2010) , 10.1029/2009JB006954
Victor N. Balashov, George D. Guthrie, J. Alexandra Hakala, Christina L. Lopano, J. Donald Rimstidt, Susan L. Brantley, Predictive modeling of CO2 sequestration in deep saline sandstone reservoirs: Impacts of geochemical kinetics Applied Geochemistry. ,vol. 30, pp. 41- 56 ,(2013) , 10.1016/J.APGEOCHEM.2012.08.016