Steric effects in the design of chiral Schiff base–titanium complexes: new catalysts for asymmetric trimethylsilylcyanation of aldehydes
作者： Angeles Gama , Lucı́a Z. Flores-López , Gerardo Aguirre , Miguel Parra-Hake , Ratnasamy Somanathan
DOI: 10.1016/S0957-4166(02)00073-3
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摘要: New chiral Schiff base ligands derived from salicylaldehydes bearing bulky ring substituents were synthesized by reaction with various amino alcohols. These new used titanium tetraisopropoxide to study steric effects on the enantioselectivity of trimethylsilylcyanation aldehydes.
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