The dynamics of chlorine-atom reactions with polyatomic organic molecules

摘要: Chlorine atoms react with a variety of organic molecules by abstraction an H atom, making HCl and radical co-product, investigations these reactions provide large valuable body data for improved fundamental understanding the mechanisms involving polyatomic molecules. The kinetics dynamics Cl alkanes have been extensively studied both experimental computational methods, key outcomes conclusions are reviewed. These serve as benchmarks interpretation recent on heteroatom functionalized such alcohols, ethers, amines, alkyl halides thiols. Although bearing many similarities to alkane reactions, significant differences found: in particular, extent rotational excitation from is much greater than very cold distribution...