Nonlinear optical and electro-optic properties of hybrid sol–gels doped with organic chromophores
作者： Hongxi Zhang , Dong Lu , Mahmoud Fallahi
DOI: 10.1016/J.OPTMAT.2005.05.016
关键词:
摘要: This paper reports a systematic investigation on the nonlinear and electro-optic properties of hybrid sol–gel doped with azo-type chromophores. The host is based photosensitive prepared from 3-(methacryloxy)propyl trimethoxysilane-zirconium (or aluminum) oxide (MAPTMS-Zr(Al)) system. chromophores are incorporated into as both guest side-chain. Second harmonic generation experiment conducted to optimize poling parameters for active films. stability second-order optical coefficients investigated by temporal decay test heat-cool cycling at elevated temperature. Electro-optic channel waveguides have been fabricated direct ultra-violet exposure, blue laser writing, reverse-mesa methods. effect measured 1550 nm intensity modulation has demonstrated. All results show that sol–gels promising media devices integrated optics in performance fabrication flexibility.
elsevier.com
sci-hub.se 参考文章(20)
Amnon Yariv, Optical electronics in modern communications Oxford University Press. ,(1997)
Daniel B. Wolfe, J. Christopher Love, Byron D. Gates, George M. Whitesides, Richard S. Conroy, Mara Prentiss, Fabrication of planar optical waveguides by electrical microcontact printing Applied Physics Letters. ,vol. 84, pp. 1623- 1625 ,(2004) , 10.1063/1.1651329
O.V. Mishechkin, D. Lu, M. Fallahi, Reliability improvement of hybrid organic-inorganic waveguides by dielectric passivation lasers and electro-optics society meeting. ,vol. 2, pp. 674- 675 ,(2003) , 10.1109/LEOS.2003.1252980
Hwan Kyu Kim, Su-Jin Kang, Sam-Kwon Choi, Yu-Hong Min, Choon-Sup Yoon, Highly Efficient Organic/Inorganic Hybrid Nonlinear Optic Materials via Sol−Gel Process: Synthesis, Optical Properties, and Photobleaching for Channel Waveguides Chemistry of Materials. ,vol. 11, pp. 779- 788 ,(1999) , 10.1021/CM980652A
Sang-Shin Lee, S.M. Garner, V. Chuyanov, Hua Zhang, W.H. Steier, Fang Wang, L.R. Dalton, A. Udupa, H.R. Fetterman, Optical intensity modulator based on a novel electrooptic polymer incorporating high /spl mu//spl beta/ chromophore IEEE Journal of Quantum Electronics. ,vol. 36, pp. 527- 532 ,(2000) , 10.1109/3.842093
Jan Vydra, Hanno Beisinghoff, Theo Tschudi, Manfred Eich, Photodecay mechanisms in side chain nonlinear optical polymethacrylates Applied Physics Letters. ,vol. 69, pp. 1035- 1037 ,(1996) , 10.1063/1.116922
Hélène Goudket, Michael Canva, Yves Lévy, Frédéric Chaput, Jean-Pierre Boilot, Temperature dependence of second-order nonlinear relaxation of a poled chromophore-doped sol–gel material Journal of Applied Physics. ,vol. 90, pp. 6044- 6047 ,(2001) , 10.1063/1.1416865
Frederic Chaumel, Hongwei Jiang, Ashok Kakkar, None, Sol−Gel Materials for Second-Order Nonlinear Optics Chemistry of Materials. ,vol. 13, pp. 3389- 3395 ,(2001) , 10.1021/CM011017Z
Osamu Watanabe, Masaaki Tsuchimori, Akane Okada, Two-step refractive index changes by photoisomerization and photobleaching processes in the films of non-linear optical polyurethanes and a urethane–urea copolymer Journal of Materials Chemistry. ,vol. 6, pp. 1487- 1492 ,(1996) , 10.1039/JM9960601487
Dong Hoon Choi, Ji Hye Park, Tae Hyung Rhee, Nakjoong Kim, Sin-Doo Lee, Improved Temporal Stability of the Second-Order Nonlinear Optical Effect in a Sol−Gel Matrix Bearing an Active Chromophore Chemistry of Materials. ,vol. 10, pp. 705- 709 ,(1998) , 10.1021/CM970311H