Enhancement of the antimicrobial properties of orthorhombic molybdenum trioxide by thermal induced fracturing of the hydrates
作者： Shahram Shafaei , Daniel Van Opdenbosch , Tobias Fey , Marcus Koch , Tobias Kraus
DOI: 10.1016/J.MSEC.2015.09.069
关键词:
摘要: The oxides of the transition metal molybdenum exhibit excellent antimicrobial properties. We present preparation trioxide dihydrate (MoO3 × 2H2O) by an acidification method and demonstrate thermal phase development morphological evolution during after calcination from 25 °C to 600 °C. dehydration material was found proceed in two steps. Microbiological roll-on tests using Staphylococcus aureus, Escherichia coli Pseudomonas aeruginosa were performed exceptional activities determined for anhydrous samples with orthorhombic lattice symmetry a large specific surface area. increase area is due crack formation loss hydrate water at 300 results support proposed mechanism oxides, which based on local acidity as consequence augmented
sci-hub.se 参考文章(45)
Thorsten Bechert, Peter Steinrücke, Josef-Peter Guggenbichler, A new method for screening anti-infective biomaterials. Nature Medicine. ,vol. 6, pp. 1053- 1056 ,(2000) , 10.1038/79568
Kathrin Lorenz, Sebastian Bauer, Kai Gutbrod, Josef Peter Guggenbichler, Patrik Schmuki, Cordt Zollfrank, Anodic TiO2 nanotube layers electrochemically filled with MoO3 and their antimicrobial properties Biointerphases. ,vol. 6, pp. 16- 21 ,(2011) , 10.1116/1.3566544
John Christian Bailar, Harry Julius Emeléus, Sir Ronald Nyholm, A. F. Trotman-Dickenson, Comprehensive inorganic chemistry Pergamon Press , Compendium (Exclusive distributors in the Western Hemisphere). ,(1973)
Kai Gutbrod, Cordt Zollfrank, The photocatalytic properties of Ti–Mo oxides prepared by a simple sol–gel route Journal of Sol-Gel Science and Technology. ,vol. 66, pp. 112- 119 ,(2013) , 10.1007/S10971-013-2973-1
Cordt Zollfrank, Kai Gutbrod, Peter Wechsler, Josef Peter Guggenbichler, Antimicrobial activity of transition metal acid MoO3 prevents microbial growth on material surfaces Materials Science and Engineering: C. ,vol. 32, pp. 47- 54 ,(2012) , 10.1016/J.MSEC.2011.09.010
N. Boudjada, J. Rodrı́guez-Carvajal, M. Anne, M. Figlarz, Dehydration of MoO3 · 2H2O: A Neutron Thermodiffractometry Study Journal of Solid State Chemistry. ,vol. 105, pp. 211- 222 ,(1993) , 10.1006/JSSC.1993.1209
A. Oed, Position-sensitive detector with microstrip anode for electron multiplication with gases Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment. ,vol. 263, pp. 351- 359 ,(1988) , 10.1016/0168-9002(88)90970-9
P. Bénard, L. Seguin, D. Louër, M. Figlarz, Structure of MoO3 · 1/2H2O by Conventional X-Ray Powder Diffraction Journal of Solid State Chemistry. ,vol. 108, pp. 170- 176 ,(1994) , 10.1006/JSSC.1994.1026
G. Mestl, T. K. K. Srinivasan, H. Knoezinger, Mechanically Activated MoO3. 3. Characterization by Vibrational Spectroscopy Langmuir. ,vol. 11, pp. 3795- 3804 ,(1995) , 10.1021/LA00010A033
Aviva Levina, Andrew I. McLeod, Jan Seuring, Peter A. Lay, Reactivity of potential anti-diabetic molybdenum(VI) complexes in biological media: A XANES spectroscopic study Journal of Inorganic Biochemistry. ,vol. 101, pp. 1586- 1593 ,(2007) , 10.1016/J.JINORGBIO.2007.07.016