Nanostructured cementitious sol gel coating on graphite for application in monolithic refractory composites

作者: S. Mukhopadhyay , G. Das , I. Biswas

DOI: 10.1016/J.CERAMINT.2011.09.006

关键词:

摘要: A nanostructured sol gel coating of calcium aluminate (CaAl2O4) over flaky graphite has been prepared by a hybrid set precursors. X-ray diffraction (XRD), Fourier transformed infrared spectroscopy (FTIR), differential thermal analysis (DTA), particle size distribution and microstructural studies have performed to understand the phase evolution its related characteristics. The topography aspects coated uncoated graphites differentiated atomic force microscopy (AFM) scanning electron (SEM) with energy dispersive spectral (EDS) analysis. FTIR XRD patterns both also investigated substantiate thin extended hydrophilic film ones. better oxidation resistance confirmed thermogravimetric (TGA). Improved water-wettability examined ‘ball-in-hand’ test for moisture requirement during installation high alumina based refractory castable composite containing that graphite. Green bulk density cubes determined corroborate performance aluminate.

参考文章(30)
G. Urretavizcaya, A. L. Cavalieri, J. M. Porto López, I. Sobrados, J. Sanz, Thermal Evolution of Alumina Prepared by the Sol-Gel Technique Journal of Materials Synthesis and Processing. ,vol. 6, pp. 1- 7 ,(1998) , 10.1023/A:1022674107059
C. Jeffrey Brinker, George W. Scherer, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing ,(1990)
Lisa C. Klein, Edward J. A. Pope, 済夫 作花, Sol-Gel Science and Technology ,(1995)
D. Kundu, T. Manna, G. De, Preparation and Characterization of Thin Optically Transparent Alumina and Ce-doped Alumina Journal of Sol-Gel Science and Technology. ,vol. 23, pp. 145- 150 ,(2002) , 10.1023/A:1013703602051
F. M. Lea, P. C. Hewlett, Lea's chemistry of cement and concrete Butterworth-Heinemann. ,(1998)
M.F. Zawrah, N.M. Khalil, Synthesis and characterization of calcium aluminate nanoceramics for new applications Ceramics International. ,vol. 33, pp. 1419- 1425 ,(2007) , 10.1016/J.CERAMINT.2006.04.022
Lori Kerns, Michael C Weinberg, Sharon Myers, Roger Assink, Al coordination in sol–gel and conventional calcium aluminate glasses Journal of Non-crystalline Solids. ,vol. 232, pp. 86- 92 ,(1998) , 10.1016/S0022-3093(98)00376-7
A. Banerjee, S. Das, S. Misra, S. Mukhopadhyay, Structural analysis on spinel (MgAl2O4) for application in spinel-bonded castables Ceramics International. ,vol. 35, pp. 381- 390 ,(2009) , 10.1016/J.CERAMINT.2007.11.009
Mehmet A. Gulgun, Oludele O. Popoola, Waltraud M. Kriven, Chemical Synthesis and Characterization of Calcium Aluminate Powders Journal of the American Ceramic Society. ,vol. 77, pp. 531- 539 ,(1994) , 10.1111/J.1151-2916.1994.TB07026.X