Nucleation Rates in a New Phenomenological Model

摘要: In this paper we develop a new theory to evaluate the nucleation rate in framework of EMLD-DNT model. Beyond model, our deals with cluster translation and exclusion, effects that have been virtually ignored classical theory. We apply model case 1-pentanol, compare predictions experimental results. find an excellent agreement between predicted by data. The distinguishing feature is its ability predict successfully formation critical nucleus without use intermolecular potential, employing only macroscopic thermodynamic properties.