Electrochemical oxidation of guanosine formation of some novel guanine oligonucleosides
作者： P. Subramanian , Glenn Dryhurst
DOI: 10.1016/0022-0728(87)85089-1
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摘要: Abstract The electrochemical oxidation of guanosine has been studied in aqueous phosphate buffer solutions at a pyrolytic graphite electrode. primary electrooxidation step appears to involve 1 e−, H+ reaction leading free radical with the unpaired electron being located C8-position. This reacts and water yield several other radicals which then undergo series chemical reactions yielding some novel guanine di- tri-nucleosides.
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