Isolation of long-chain aliphatic alcohols from beeswax using lipase-catalyzed methanolysis in supercritical carbon dioxide
作者： Michael A. Jackson , Fred J. Eller
DOI: 10.1016/J.SUPFLU.2005.08.008
关键词:
摘要: Aliphatic alcohols of chain lengths 24-34 carbons have been found to be beneficial in treating hypercholesterolemia. Approximately 40% beeswax is long-chain esters which can transesterified supercritical carbon dioxide give these and fatty acid methyl esters. The methanolysis reaction was catalyzed by an immobilized lipase from Candida antarctica flowing the were then isolated precipitation heptane. following percentages: tetracosanol, 9.1; hexacosanol, 14.0; octacosanol, 18.4; triacontanol, 37.2; dotriacontanol, 21.1; tetratriacontanol, 0.3. utility method demonstrated isolating jojoba oil a mixture triglycerides waxes corn bran.
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Johanna C Taylor, Lisa Rapport, G.Brian Lockwood, Octacosanol in human health Nutrition. ,vol. 19, pp. 192- 195 ,(2003) , 10.1016/S0899-9007(02)00869-9
A.R. Mesa, R. Más, M. Noa, C. Hernández, I. Rodeiro, R. Gámez, M. García, A. Capote, C.L. Alemán, Toxicity of policosanol in beagle dogs: one-year study Toxicology Letters. ,vol. 73, pp. 81- 90 ,(1994) , 10.1016/0378-4274(94)90098-1
Celia L AlemAn, Rosa Más, Caridad Hernández, Idania Rodeiro, Eloisa Cerejido, Miriam Noa, Amelia Capote, Roberto Menéndez, Ana Amor, Vivian Fraga, Vivian Sotolongo, Sonia Jiménez, A 12-month study of policosanol oral toxicity in Sprague Dawley rats. Toxicology Letters. ,vol. 70, pp. 77- 87 ,(1994) , 10.1016/0378-4274(94)90147-3
Gladys Castaño, Rosa Más, Manuel Nodarse, José Illnait, Lilla Fernández, Julio César Fernández, One-year study of the efficacy and safety of policosanol (5 mg twice daily) in the treatment of type II hypercholesterolemia Current Therapeutic Research-clinical and Experimental. ,vol. 56, pp. 296- 304 ,(1995) , 10.1016/0011-393X(95)85034-1
R. D. Plattner, G. F. Spencer, Chemical lonization mass spectrometry of wax esters Lipids. ,vol. 18, pp. 68- 73 ,(1983) , 10.1007/BF02534693
Jawwad A. Darr, Martyn Poliakoff, New Directions in Inorganic and Metal-Organic Coordination Chemistry in Supercritical Fluids Chemical Reviews. ,vol. 99, pp. 495- 542 ,(1999) , 10.1021/CR970036I
Michael A. Jackson, Jerry W. King, Methanolysis of seed oils in flowing supercritical carbon dioxide Journal of the American Oil Chemists' Society. ,vol. 73, pp. 353- 356 ,(1996) , 10.1007/BF02523430
Terry A. Isbell, Derivatives of New Crop Oils ChemInform. ,vol. 31, ,(2000) , 10.1002/CHIN.200029262
S. L. Taylor, J. W. King, Optimization of the extraction and fractionation of corn bran oil using analytical supercritical fluid instrumentation. Journal of Chromatographic Science. ,vol. 38, pp. 91- 94 ,(2000) , 10.1093/CHROMSCI/38.3.91
Peter Licence, Jie Ke, Maia Sokolova, Stephen K. Ross, Martyn Poliakoff, Chemical reactions in supercritical carbon dioxide: from laboratory to commercial plant Green Chemistry. ,vol. 5, pp. 99- 104 ,(2003) , 10.1039/B212220K