H2O2/SOCl2: a useful reagent system for the conversion of thiocarbonyls to carbonyl compounds

作者: Kiumars Bahrami , Mohammad M. Khodaei , Azita Farrokhi

DOI: 10.1016/J.TET.2009.06.110

关键词:

摘要: Abstract The H2O2/SOCl2 reagent system has been used as a new and efficient for deprotection of thiocarbonyls to carbonyl compounds. salient features this protocol are short reaction times, good chemoselectivity, clean profiles, simple work-up that preclude the use toxic solvents.

参考文章(35)
Richard C. Larock, Reagents for Organic Synthesis ,(1967)
V. Bhat, M. V. George, Photooxygenation of aziridines and some potential azomethine ylides ChemInform. ,vol. 11, pp. 3288- 3292 ,(1979) , 10.1021/JO01333A002
Jie Gao, Guan-Wu Wang, Direct oxidative amidation of aldehydes with anilines under mechanical milling conditions. Journal of Organic Chemistry. ,vol. 73, pp. 2955- 2958 ,(2008) , 10.1021/JO800075T
Kiumars Bahrami, M. Mehdi Khodaei, Fardin Naali, Mild and Highly Efficient Method for the Synthesis of 2-Arylbenzimidazoles and 2-Arylbenzothiazoles Journal of Organic Chemistry. ,vol. 73, pp. 6835- 6837 ,(2008) , 10.1021/JO8010232
Masaharu Hashimoto, Yasushi Obora, Satoshi Sakaguchi, Yasutaka Ishii, Beckmann Rearrangement of Ketoximes to Lactams by Triphosphazene Catalyst Journal of Organic Chemistry. ,vol. 73, pp. 2894- 2897 ,(2008) , 10.1021/JO702277G
Hanan Al-Awadi, Maher R. Ibrahim, Hicham H. Dib, Nouria A. Al-Awadi, Yehia A. Ibrahim, Gas-phase thermolysis of 1-acylnaphtho[1,8-de][1,2,3]triazines. Interesting direct routes towards condensed naphtho[1,8-de]heterocyclic ring systems Tetrahedron. ,vol. 61, pp. 10507- 10513 ,(2005) , 10.1016/J.TET.2005.08.047
Junichi TANI, Toyonari OINE, Ichizo INOUE, A Convenient Method of Amidation of Carboxylic Acids Using Boron Trifluoride Etherate Synthesis. ,vol. 1975, pp. 714- 715 ,(1975) , 10.1055/S-1975-23900
George A. Olah, Massoud Arvanaghi, Lena Ohannesian, G. K. Surya Prakash, Thiocarbonyl to Carbonyl Group Transformation with Nitrosonium Tetrafluoroborate Synthesis. ,vol. 1984, pp. 785- 786 ,(1984) , 10.1055/S-1984-30974