The effect of temperature on the synthesis of BN nanocrystals
作者： Xiaopeng Hao , Meiyan Yu , Deliang Cui , Xiangang Xu , Qilong Wang
DOI: 10.1016/S0022-0248(02)01291-5
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摘要: Abstract Boron nitride (BN) nanocrystals have been synthesized by the reaction of Li3N and BBr3 in organic solvent. The experimental results indicated that, at low temperature, hexagonal BN (hBN) is dominant phase sample. content cubic (cBN) increased with it reached a maximum 480°C. As temperature further, cBN decreased, hBN became again. This phenomenon was discussed briefly this paper.
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M. Gasgnier, H. Szwarc, A. Ronez, Low-energy ball-milling: Transformations of boron nitride powders. Crystallographic and chemical characterizations Journal of Materials Science. ,vol. 35, pp. 3003- 3009 ,(2000) , 10.1023/A:1004735011914
Lin Rao, Richard B. Kaner, Rapid Solid-State-Precursor Synthesis of Crystalline Boron Nitride Inorganic Chemistry. ,vol. 33, pp. 3210- 3211 ,(1994) , 10.1021/IC00093A003
X. P. Hao, D. L. Cui, G. X. Shi, Y. Q. Yin, X. G. Xu, J. Y. Wang, M. H. Jiang, X. W. Xu, Y. P. Li, B. Q. Sun, Synthesis of Cubic Boron Nitride at Low-Temperature and Low-Pressure Conditions Chemistry of Materials. ,vol. 13, pp. 2457- 2459 ,(2001) , 10.1021/CM010079M
S. Bohr, R. Haubner, B. Lux, Comparative aspects of c-BN and diamond CVD Diamond and Related Materials. ,vol. 4, pp. 714- 719 ,(1995) , 10.1016/0925-9635(94)05224-7
T. Ishii, T. Sato, Y. Sekikawa, M. Iwata, Growth of whiskers of hexagonal boron nitride Journal of Crystal Growth. ,vol. 52, pp. 285- 289 ,(1981) , 10.1016/0022-0248(81)90206-2
J.P. Rivière, Y. Pacaud, M. Cahoreau, Spectroscopic studies of BN films deposited by dynamic ion mixing Thin Solid Films. ,vol. 227, pp. 44- 53 ,(1993) , 10.1016/0040-6090(93)90185-R
Satoshi Nakano, Osamu Fukunaga, New scope of high pressure-high temperature synthesis of cubic boron nitride☆ Diamond and Related Materials. ,vol. 2, pp. 1409- 1413 ,(1993) , 10.1016/0925-9635(93)90149-V
Laurence Vel, Gérard Demazeau, Jean Etourneau, Cubic boron nitride: synthesis, physicochemical properties and applications Materials Science and Engineering B-advanced Functional Solid-state Materials. ,vol. 10, pp. 149- 164 ,(1991) , 10.1016/0921-5107(91)90121-B
A. V. Kurdyumov, V. L. Solozhenko, W. B. Zelyavski, Lattice Parameters of Boron Nitride Polymorphous Modifications as a Function of Their Crystal-Structure Perfection Journal of Applied Crystallography. ,vol. 28, pp. 540- 545 ,(1995) , 10.1107/S002188989500197X
P.B. Mirkarimi, K.F. McCarty, D.L. Medlin, W.G. Wolfer, T.A. Friedmann, E.J. Klaus, G.F. Cardinale, D.G. Howitt, On the role of ions in the formation of cubic boron nitride films by ion-assisted deposition Journal of Materials Research. ,vol. 9, pp. 2925- 2938 ,(1994) , 10.1557/JMR.1994.2925