Determination and modeling of the solubility of (limonin in methanol or acetone+water) binary solvent mixtures at T =283.2K to 318.2K
作者： Jie-Ping Fan , Bing Zheng , Dan-Dan Liao , Jia-Xin Yu , Ya-Hui Cao
DOI: 10.1016/J.JCT.2016.03.037
关键词:
摘要: Abstract The solubility of limonin in the binary solvent mixtures (methanol + water) and (acetone + water) with various initial mole fractions methanol or acetone was measured by high-performance liquid chromatography (HPLC) at different temperatures ranging from 283.2 K to 318.2 K. increased increasing fraction mixtures, whereas it had a maximum point 0.9 mol mixtures. temperature two correlated van’t Hoff model modified Apelblat model, fitting results showed that better correlation. CNIBS/Redlich–Kister simplified were used correlate data composition, show reveals agreement experimental values. Furthermore, illustrate effects both composition on changes limonin, values fitted Jouyban–Acree, Hoff–Jouyban–Acree, Apelblat–Jouyban–Acree, Ma Sun models. Among five models, Jouyban–Acree give best correlation for while system most accurately Hoff–Jouyban–Acree model.
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