UV-visible spectroscopic study of the salicyladehyde benzoylhydrazone and its cobalt complexes.
作者： Yi-Heng Lu , Yu-Wei Lu , Cheng-Li Wu , Qun Shao , Xiao-Ling Chen
DOI: 10.1016/J.SAA.2005.12.032
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摘要: Abstract Salicyladehyde benzoylhydrazone (SBH) has three groups suitable for forming coordination bond with transition metal. The UV–vis absorption spectra of SBH and its Co(II) complexes in various media were studied by using the deconvolution method. It is found that structure complex solution different from those solid crystals. nature depends on acidity phenolic proton medium. In neutral or slightly acid medium, a non-charged bidentate ligand. And “free” hydroxyl group molecule makes it possible to form hydrogen bonds solution. basic mono, negatively charged tridentates
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John T Edward, Partition coefficients of the iron (III) complexes of pyridoxal isonicotinoyl hydrazone and its analogs and the correlation to iron chelation efficacy. Correction of some reported partition coefficients Biometals. ,vol. 11, pp. 203- 205 ,(1998) , 10.1023/A:1009264421478
Debbie C Crans, Chemistry and insulin-like properties of vanadium(IV) and vanadium(V) compounds. Journal of Inorganic Biochemistry. ,vol. 80, pp. 123- 131 ,(2000) , 10.1016/S0162-0134(00)00048-9
Amna S. A. Zidan, Synthesis and Investigation of Mixed‐Ligand Transition Metal Complexes of Alkyl Dithiocarbonate and Benzoylhydrazine or Benzoylhydrazone Derivatives Synthesis and Reactivity in Inorganic and Metal-organic Chemistry. ,vol. 34, pp. 743- 762 ,(2004) , 10.1081/SIM-120035954
Yaofeng Yuan, Zhong Cao, Nanyan Fu, Jitao Wang, Linhong Weng, Antonio Bezerra de Carvalho, Clovis Peppe, Preparation, characterization, electrochemical studies and crystal structure determination of salicylaldehyde–aroylhydrazone, ferrocenyl–aroylhydrazone and salicylaldehyde–ferrocenoylhydrazone complexes of indium Journal of Organometallic Chemistry. ,vol. 637, pp. 631- 641 ,(2001) , 10.1016/S0022-328X(01)00961-5
Y LU, A novel methodology for evaluation of formation constants of complexes: example of lanthanide-Arsenazo III complexes. Talanta. ,vol. 62, pp. 959- 970 ,(2004) , 10.1016/J.TALANTA.2003.10.030
C. C. Gatto, E. Schulz Lang, A. Kupfer, A. Hagenbach, Ulrich Abram, Mono-, Di- and Trinuclear Dioxo Complexes of Uranium Containing Hydrazonato and Azomethine Ligands Zeitschrift für anorganische und allgemeine Chemie. ,vol. 630, pp. 1286- 1295 ,(2004) , 10.1002/ZAAC.200400103
E. Vauthier, F. Maurel, T. Couesnon, A. Cossé-Barbi, IR Study of Complex Between Salicylalbenzoylhydrazone (SBH) and Iron III: Normal Mode Assignment Assisted by Quantum Mechanical Calculation Spectroscopy Letters. ,vol. 32, pp. 505- 517 ,(1999) , 10.1080/00387019909350002
A. Lyubchova, N. Jouini, A. Massat, J. P. Doucet, K. Boubekeur, A. Cossé-Barbi, Structure of di(salicylaldehyde benzoylhydrazonato) zinc (II), an unusual staircase polymeric structure formed via E → Z isomerization on complexation Zeitschrift Fur Kristallographie. ,vol. 216, pp. 556- 559 ,(2001) , 10.1524/ZKRI.216.10.556.20370
M.F Iskander, T.E Khalil, R Werner, W Haase, I Svoboda, H Fuess, Synthesis, reactivity and magnetochemical studies on copper(II) complexes derived from N-salicylidenearoylhydrazines. X-ray structure of [mononitratoOO(−1)(N-salicylidenatobenzoylhydrazine)ONO(−1)]copper(II) monohydrate Polyhedron. ,vol. 19, pp. 949- 958 ,(2000) , 10.1016/S0277-5387(00)00340-5
P.B. Sreeja, M.R.Prathapachandra Kurup, Synthesis and spectral characterization of ternary complexes of oxovanadium(IV) containing some acid hydrazones and 2,2'-bipyridine. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 61, pp. 331- 336 ,(2005) , 10.1016/J.SAA.2004.04.001