I. Experimental Facts: Water‐Nonionic Surfactant Systems, and the Effect of Additives

作者: R. Strey

DOI: 10.1002/BBPC.19961000303

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摘要: In this introductory article we approach microemulsions from the binary water-surfactant side. Model systems of water - nonionic surfactant (CiEj) type are examined. Many features observable in these systems. As such discuss dependence cloud points on i and j, temperature viscosity within micellar phase, formation dilute bilayer phases. The effect additives is examined, as it permits to gain insight into structures interactions. Towards end paper most important additive for microemulsion formation, oil, considered. A special feature long-chain surfactants highlighted, namely, non-monotonic critical lines leading very peculiar two-phase lobes precursors three-phase bodies.

参考文章(23)
C. Thunig, H. Hoffmann, G. Platz, Iridescent colours in surfactant solutions Steinkopff. pp. 297- 307 ,(1989) , 10.1007/BFB0116225
Edwin J. Staples, Gordon J. T. Tiddy, Nuclear magnetic resonance technique to distinguish between micelle size changes and secondary aggregation in anionic and nonionic surfactant solutions Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. ,vol. 74, pp. 2530- 2541 ,(1978) , 10.1039/F19787402530
R. Triolo, L. J. Magid, J. S. Johnson, H. R. Child, Small-angle neutron scattering from aqueous micellar solutions of a nonionic surfactant as a function of temperature The Journal of Physical Chemistry. ,vol. 86, pp. 3689- 3695 ,(1982) , 10.1021/J100216A004
Kōzō Shinoda, T Ogawa, The solubilization of water in nonaqueous solutions of nonionic surfactants Journal of Colloid and Interface Science. ,vol. 24, pp. 56- 60 ,(1967) , 10.1016/0021-9797(67)90276-7
R. Menes, S. A. Safran, R. Strey, Reentrant Phase Separation in Microemulsions. Physical Review Letters. ,vol. 74, pp. 3399- 3402 ,(1995) , 10.1103/PHYSREVLETT.74.3399
R. Strey, Microemulsion microstructure and interfacial curvature Colloid and Polymer Science. ,vol. 272, pp. 1005- 1019 ,(1994) , 10.1007/BF00658900
Fuminiro Harusawa, Shin Nakamura, Takeo Mitsui, Phase equilibria in the water-dodecane-pentaoxyethylene dodecylether system Colloid and Polymer Science. ,vol. 252, pp. 613- 619 ,(1974) , 10.1007/BF01558159
H Saito, K Shinoda, The solubilization of hydrocarbons in aqueous solutions of nonionic surfactants Journal of Colloid and Interface Science. ,vol. 24, pp. 10- 15 ,(1967) , 10.1016/0021-9797(67)90271-8
M. Jonstroemer, R. Strey, Nonionic bilayers in dilute solutions: effect of additives The Journal of Physical Chemistry. ,vol. 96, pp. 5993- 6000 ,(1992) , 10.1021/J100193A064
M Kahlweit, R Strey, D Haase, None, Phase behavior of multicomponent systems water-oil-amphiphile-electrolyte. 3. The Journal of Physical Chemistry. ,vol. 89, pp. 163- 171 ,(1985) , 10.1021/J100247A034