Unexpected coupling reaction of (F-alkyl)iodides with 1-bromo-1-octyne: access to 1-(F-alkyl)-1-octynes
作者： Véronique Sanchez , Jacques Greiner
DOI: 10.1016/0022-1139(93)02998-T
关键词:
摘要: Abstract ( F -Alkyl)iodides react with 1-bromo-1-octyne in the presence of a radical initiator [α,α'-azobis(isobutyronitrile)] to give mainly coupling products, 1-( -alkyl)-1-octynes.
elsevier.com
sci-hub.se 参考文章(18)
Teruo Umemoto, Yoshihiko Gotoh, Perfluoroalkylations of carbanions with (perfluoroalkyl)-phenyliodonium triflates (FITS reagents). Bulletin of the Chemical Society of Japan. ,vol. 59, pp. 439- 445 ,(1986) , 10.1246/BCSJ.59.439
Leila Zarif, Jacques Greiner, Simonne Pace, Jean G. Riess, Synthesis of perfluoroalkylated xylitol ethers and esters: new surfactants for biomedical uses Journal of Medicinal Chemistry. ,vol. 33, pp. 1262- 1269 ,(1990) , 10.1021/JM00166A028
Zhen-Yu Yang, Donald J. Burton, Palladium-catalyzed reaction of fluorinated vinyl iodides with terminal alkynes: a new and general route to fluorinated enynes Journal of Fluorine Chemistry. ,vol. 53, pp. 307- 326 ,(1991) , 10.1016/S0022-1139(00)80956-2
Seijiro Matsubara, Makoto Mitani, Kiitiro Utimoto, A facile preparation of 1-perflouroalkylalkenes and alkynes. Palladium catalyzed reaction of perfluoroalkyl iodides with organotin compounds Tetrahedron Letters. ,vol. 28, pp. 5857- 5860 ,(1987) , 10.1016/S0040-4039(01)81073-X
Andrew E. Feiring, Reaction of perfluoroalkyl iodides with electron-donor nucleophiles. Addition of perfluoroalkyl iodides to olefins initiated by electron transfer The Journal of Organic Chemistry. ,vol. 50, pp. 3269- 3274 ,(1985) , 10.1021/JO00218A006
Neal O. Brace, Some approaches to the synthesis of fluorinated alcohols and esters. II. Use of F-alkyl iodides for the synthesis of F-alkyl alkanols Journal of Fluorine Chemistry. ,vol. 20, pp. 313- 327 ,(1982) , 10.1016/S0022-1139(00)82223-X
J.J. Mielcarek, J.G. Morse, K.W. Morse, A new synthesis for fluoroacetylenes. Potassium fluoride as a dehydroiodination agent. Journal of Fluorine Chemistry. ,vol. 12, pp. 321- 324 ,(1978) , 10.1016/S0022-1139(00)82849-3
J. Greiner, A. Milius, J.G. Riess, Addition of perfluoroalkyl iodides to 4-pentenol and its derivatives: one-pot preparation of 2-[(F-alkyl)methyl]tetrahydrofurans Journal of Fluorine Chemistry. ,vol. 56, pp. 285- 293 ,(1992) , 10.1016/S0022-1139(00)81175-6
Tuyêt Jeffery, Copper(I) and phase transfer catalysed allylic substitution by terminal alkynes Tetrahedron Letters. ,vol. 30, pp. 2225- 2228 ,(1989) , 10.1016/S0040-4039(00)99654-0
J N Bruneton, M N Falewée, E François, P Cambon, C Philip, J G Riess, C Balu-Maestro, A Rogopoulos, Liver, spleen, and vessels: preliminary clinical results of CT with perfluorooctylbromide. Radiology. ,vol. 170, pp. 179- 183 ,(1989) , 10.1148/RADIOLOGY.170.1.2909093